HomeMy WebLinkAboutHeraeus Medevio Report Liquid Storage Room FINAL1
Fire Protection Report – Heraeus Medevio
Linda D. French, F PE
Summary
Heraeus Medevio is a contract medical device manufacturer and development partner. The company brings
lifesaving and life-changing medical devices to market through partnerships with medical device
manufacturing companies, and is backed by Heraeus Group, a family-owned global technology company
headquartered in Hanau, Germany. Heraeus Medevio is located at 48 Northern Stacks Drive in Fridley,
Minnesota. The existing facility is approximately 63,400 sqft.
Heraeus Medevio would like to add an H-3 Liquid Storage Room to store and use the flammable liquids. A
Fire Protection Code Analysis will be completed to determine the Maximum Allowable Quantities (MAQs)
and the protection required to store the flammable and combustible liquids.
Building Information
• Existing Building Construction Type II-B Noncombustible Construction – Block Construction & Steel
Bar Joist Roof
• Total Building Area– 118,400 ft2
• Building Occupancy Classification – Group S-1, Group B, Group F-1 and Group H-2
• Existing Axalta Mixing and Storage Room of 8,500 ft2
• Existing Sprinkler System
o ESFR Sprinkler System protects entire building to protect Class I-IV and Unexpanded exposed
Plastics
K17 ESFR Sprinkler Heads @ 52 psi with 250 gpm hose allowance
o Foam Sprinkler System protects existing Axalta Mixing and Storage Room
The building has an overall footprint of 118,400 ft2. Full automatic fire sprinkler protection is provided
throughout, and the building meets the requirements of MSBC 507.4 as an unlimited area building. Heraeus
Medevio’s tenant space is approximately 63,400 ft2 and Axalta’s tenant space is approximately 55,000 ft2.
Because the building is unlimited area, Group H occupancies must comply with the allowable area
requirements of MSBC 507.8. As such, the maximum combined area of all Group H occupancies within the
building must not exceed 10% of the building area, or 11,840 ft2. Additionally, Group H occupancies within
the space must also meet the allowable area requirements of MSBC Table 503. The allowable area of the
Group H occupancies can be increased due to frontage in accordance with MSBC 506.2.
Axalta Tenant Space
As a Group H-2 occupancy in a Type IIB building, the existing Axalta storage room is limited to 7,000 ft2 plus
a frontage increase for having more than the required 25% of the room perimeter located on the exterior of
the building. The existing mixing and storage room is located at the corner of the building with 50% of the
room perimeter located on exterior walls. As such, a 25% increase in allowable area is applied (50%
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provided - 25% required = 25% increase) to the 7,000 ft2 maximum. With the frontage increase, the
maximum allowable area of the existing Axalta mixing & storage room is 8,750 ft2. The actual area of the
existing mixing & storage room is only 8,500 ft2. As all Group H areas are aggregated together to determine
the most restrictive allowable height, area, and building construction type, this leaves 250 sqft available for
a new hazardous occupancy.
Heraeus Medevio Tenant Space
In a Type IIB unlimited area building, in accordance with MSBC 507.8, the maximum combined area of all
Group H occupancies within the building must not exceed 10% of the building area and must also meet the
allowable area requirements of MSBC Table 503. The allowable area of the Group H occupancies can also be
increased due to frontage in accordance with MSBC 506.2. With the existing H-2 Mixing and Storage Room
in Axalta’s tenant space, Heraeus Medevio is limited to a maximum H-3 room 250 ft2. Heraeus Medevio is
requesting to add an H-3 storage room of 110 ft2.
Figure 1. 48 Northern Stacks Proposed H Occupancies
As shown in Figure 2, Heraeus Medevio will store 55-gallon drums of 99% and 70% Isopropyl Alcohol and
one gallon glass bottles of Methanol and Acetone on shelves in cartons in a new liquid storage room. The
containers will be stored normally closed. There will also be two 55-gallon drums, one 99% Isopropyl
Alcohol and one 70% Isopropyl Alcohol, connected to an inert gas pneumatic pump with a regulator that
will transfer the liquid from the 55-gallon drum to 5-gallon safety lab can. The normal pressure will be less
than 15 psi. The safety lab cans will be filled via a piped system to the dispensing valve located at the wall of
the liquid storage room. This process is considered a closed system and therefore is considered “closed
use” per the 2020 Minnesota State Fire Code. IAW table 5003.1.1(1), as the storage room will be
sprinklered, a maximum of 240 gallons of Class IB liquids can be “in closed use” per control area.
Figure 2. Heraeus Medevio Flammable Liquid Storage Room Layout.
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There will also be two 55-gallon drums used to collect waste comprised of isopropyl alcohol/water mix and
methanol/sulfuric acid mix located in the nitinol room. These drums are equipped with a steel drum safety
funnel equipped with a flame arrester and self-closing cover. The drums are located on
a spill pallet with a capacity to contain a spill of 70 gallons. The process of transferring
the waste liquid into the funnel is considered “open use”. IAW Table 5003.1.1(1), as
the warehouse is sprinklered, a maximum of 60 gallons “in open use” is permitted per
control area. Figure 3 shows the locations where the Class IB liquids will be stored and
dispensed in the Heraeus Medevio facility.
Figure 3. Heraeus Medevio Areas for Storage and Dispensing of Class IB Flammable Liquids.
Heraeus Medevio can store up to 480 gallons of Class IB Flammable liquids in the sprinklered warehouse
area in approved liquid storage cabinets IAW Table 5003.1.1(1). As stated above, there will also be two 55-
gallon drums of Class IB liquid waste in the Nitinol Room which are normally closed except for when waste
is being added to the drum through the attached safety funnel. Only one of these drums will be in “open
use” at a time. The remaining permitted 5 gallons of Class IB liquids will be “in use” in the facility at
workstations. This leaves a maximum of 365 gallons of Class IB liquids permitted to be stored in the
warehouse control area in approved cabinets. There will be a maximum of three flammable liquid storage
cabinets located in the warehouse control area to store up to six additional 55-gallon drums of Class IB
Liquids. This leaves 35 gallons that can be stored in 5-gallon safety cans in the warehouse control area.
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Code Analysis
2020 MINNESOTA STATE FIRE CODE CHAPTER 50
SECTION 5003 General Requirements
Table 1 lists the hazardous materials and quantities of hazardous materials that will be stored and used in
the Heraeus Medevio Facility.
Table 1. Flammable Liquids to be stored.
5003.1 Scope. The storage, use and handling of all hazardous materials shall be in accordance with
this section.
5003.1.1 Maximum allowable quantity per control area. The maximum allowable quantity
per control area shall be as specified in Tables 5003.1.1(1) through 5003.1.1(4).
5003.1.3 Quantities not exceeding the maximum allowable quantity per control area. The
storage, use and handling of hazardous materials in quantities not exceeding the maximum
allowable quantity per control area indicated in Tables 5003.1.1(1) through 5003.1.1(4) shall
be in accordance with Sections 5001 and 5003. The quantities in the warehouse control area
will not exceed the MAQs if a new liquid storage room is constructed IAW MSBC and MSFC.
5003.1.4 Quantities exceeding the maximum allowable quantity per control area. The
storage and use of hazardous materials in quantities exceeding the maximum allowable
quantity per control area indicated in Tables 5003.1.1(1) through 5003.1.1(4) shall be in
accordance with this chapter.
5003.2 Systems, equipment and processes. Systems, equipment and processes utilized for
storage, dispensing, use or handling of hazardous materials shall be in accordance with
Sections 5003.2.1 through 5003.2.9.
CAS
Number
Chemical Name Physical
State
Quantity Unit of
Measurement
Total
Quantity
STORED
Total
Quantity
IN USE
CLOSED
Total
Quantity
IN USE
OPEN
Unit of
Measure
Hazard Classification
In Liquid Storage Room
67-63-0 Alcohol, Isopropyl 99% USP Liquid 5 55 Gallon Metal Drum 275 55 0 Gallons Class IB Flammable
67-63-0 Alcohol, Isopropyl 70%Liquid 4 55 Gallon Metal Drum 220 55 0 Gallons Class IB Flammable
67-64-1 Acetone Liquid 12 1 Gallon Glass Bottle 12 0 0 Gallons Class IB Flammable
67-56-1 Methanol Liquid 12 1 Gallon Glass Bottle 12 0 0 Gallons Class IB Flammable
Total in Storage Room 519 110 0 Gallons
In Warehouse In Cabinets
67-63-0 Alcohol, Isopropyl 99% USP Liquid 3 55 Gallon Metal Drum 165 0 0 Gallons Class IB Flammable
67-63-0 Alcohol, Isopropyl 70%Liquid 3 55 Gallon Metal Drum 165 0 0 Gallons Class IB Flammable
67-56-1 Methanol Liquid 0 1 Gallon Glass Bottle 0 0 0 Gallons Class IB Flammable
Total 330 0 0 Gallons
In Warehouse not in Cabinet
Waste - 50/50 mix of IPA99/H20 Liquid 1 55 Gallon Metal Drum 55 0 55 Gallons Class IB Flammable
Waste - Methanol/Sulfuric mix Liquid 1 55 Gallon Metal Drum 55 0 55 Gallons Class IB Flammable
Total 110 0 55 Gallons 1 container at a time
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5003.2.1 Design and construction of containers, cylinders and tanks. Containers,
cylinders and tanks shall be designed and constructed in accordance with approved
standards. Containers, cylinders, tanks and other means used for containment of
hazardous materials shall be of an approved type. Pressure vessels not meeting DOT
requirements for transportation shall comply with the ASME Boiler and Pressure Vessel
Code. All containers shall be constructed IAW approved standards.
5003.2.5 Empty containers and tanks. Empty containers and tanks previously used for
the storage of hazardous materials shall be free from residual material and vapor as
defined by DOT, the Resource Conservation and Recovery Act (RCRA) or other
regulating authority or maintained as specified for the storage of hazardous material.
5003.2.6 Maintenance. In addition to the requirements of Section 5003.2.3,
equipment, machinery and required detection and alarm systems associated with
hazardous materials shall be maintained in an operable condition. Defective
containers, cylinders and tanks shall be removed from service, repaired or disposed of
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in an approved manner. Defective equipment or machinery shall be removed from
service and repaired or replaced. Required detection and alarm systems shall be
replaced or repaired where defective.
5003.2.6.2 Defective containers and tanks. Defective containers and tanks
shall be removed from service, repaired in accordance with approved
standards or disposed of in an approved manner.
5003.3 Release of hazardous materials. Hazardous materials in any quantity shall not be
released into a sewer, storm drain, ditch, drainage canal, creek, stream, river, lake or tidal
waterway or on the ground, sidewalk, street, highway or into the atmosphere.
Exceptions:
1. The release or emission of hazardous materials is allowed where in compliance with
federal, state or local governmental agencies, regulations or permits.
2. The release of pesticides is allowed where used in accordance with registered label
directions.
3. The release of fertilizer and soil amendments is allowed where used in accordance
with manufacturer’s specifications.
5003.3.1 Unauthorized discharges. In the event hazardous materials are released in
quantities reportable under state, federal or local regulations, the fire code official
shall be notified and the following procedures required in accordance with Sections
5003.3.1.1 through 5003.3.1.4.
5003.3.1.1 Records. Records of the unauthorized discharge of hazardous
materials by the permittee shall be maintained.
5003.3.1.2 Preparation. Provisions shall be made for controlling and mitigating
unauthorized discharges.
5003.3.1.3 Control. Where an unauthorized discharge caused by primary
container failure is discovered, the involved primary container shall be
repaired or removed from service.
5003.3.1.4 Responsibility for cleanup. The person, firm or corporation
responsible for an unauthorized discharge shall institute and complete all
actions necessary to remedy the effects of such unauthorized discharge,
whether sudden or gradual, without cost to the jurisdiction. Where deemed
necessary by the fire code official, cleanup can be initiated by the fire
department or by an authorized individual or firm. Costs associated with such
cleanup shall be borne by the owner, operator or other person responsible for
the unauthorized discharge.
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5003.4 Safety Data Sheets. Safety Data Sheets (SDS) shall be readily available on the premises
for hazardous materials regulated by this chapter. Where a hazardous substance is developed in
a laboratory, available information shall be documented. MSDSs shall be readily available on
the premises.
5003.5 Hazard identification signs. Unless otherwise exempted by the fire code official,
visible hazard identification signs as specified in NFPA 704 for the specific material contained
shall be placed on stationary containers and aboveground tanks and at entrances to locations
where hazardous materials are stored, dispensed, used or handled in quantities requiring a
permit and at specific entrances and locations designated by the fire code official. Visible
hazard identification signs shall be placed on containers and at entrances where hazardous
materials are stored, dispensed or used.
5003.5.1 Markings. Individual containers, cartons or packages shall be conspicuously
marked or labeled in an approved manner.
5003.6 Signs. Signs and markings required by Sections 5003.5 and 5003.5.1 shall not be
obscured or removed, shall be in English as a primary language or in symbols allowed by this
code, shall be durable, and the size, color and lettering shall be approved.
5003.7 Sources of ignition. Sources of ignition shall comply with Sections 5003.7.1 through
5003.7.3.
5003.7.1 Smoking. Smoking shall be prohibited and “No Smoking” signs provided as
follows:
1. In rooms or areas where hazardous materials are stored or dispensed or
used in open systems in amounts requiring a permit in accordance with
Section 5001.5.
2. Within 25 feet of outdoor storage, dispensing or open use areas.
3. Facilities or areas within facilities that have been designated as totally no
smoking shall have “No Smoking” signs placed at all entrances to the facility or
area. Designated areas within such facilities where smoking is permitted either
permanently or temporarily, shall be identified with signs designating that
smoking is permitted in these areas only.
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4. In rooms or areas where flammable or combustible hazardous materials are
stored, dispensed or used. Signs required by this section shall be in English as a
primary language or in symbols allowed by this code and shall comply with
Section 310.
5003.7.2 Open flames. Open flames and high-temperature devices shall not be used
in a manner that creates hazardous condition and shall be listed for use with the
hazardous materials stored or used.
5003.7.3 Industrial trucks. Powered industrial trucks used in areas designated as
hazardous (classified) locations shall be in accordance with Section 309.2.
309.2 Use in hazardous (classified) locations. Powered industrial trucks used in
areas designated as hazardous (classified) locations in accordance with NFPA
70 shall be listed and labeled for use in the environment intended in
accordance with NFPA 505.
5003.8 Construction requirements. Buildings, control areas, enclosures and cabinets for
hazardous materials shall be in accordance with Sections 5003.8.1 through 5003.8.7.2.
5003.8.1 Buildings. Buildings, or portions thereof, in which hazardous materials are
stored, handled or used shall be constructed in accordance with the International
Building Code.
5003.8.2 Required detached buildings. Group H occupancies containing quantities of
hazardous materials in excess of those set forth in Table 5003.8.2 shall be in detached
buildings. The quantities do not exceed those in Table 5003.8.2.
5003.8.3 Control areas. Control areas shall comply with Sections 5003.8.3.1 through
5003.8.3.5.3.
5003.8.3.1 Construction requirements. Control areas shall be separated from
each other by fire barriers constructed in accordance with Section 707 of the
International Building Code or horizontal assemblies constructed in accordance
with Section 711 of the International Building Code, or both.
5003.8.3.2 Percentage of maximum allowable quantities. The percentage of
maximum allowable quantities of hazardous materials per control area
allowed at each story within a building shall be in accordance with Table
5003.8.3.2.
5003.8.3.3 Number. The maximum number of control areas per floor within a
building shall be in accordance with Table 5003.8.3.2.
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Four control areas are permitted. This building will have 4 control areas
including the Axalta main warehouse area, the existing Axalta mixing Room
(H-2), the Heraeus Medevio Warehouse area and the Heraeus Medevio new
liquid storage room (H-3).
5003.8.3.4 Fire-resistance-rating requirements. The required fire-resistance rating for
fire barriers shall be in accordance with Table 5003.8.3.2. The floor assembly of the
control area and the construction supporting the floor of the control area shall have a
fire-resistance rating of not less than 2 hours. The liquid storage room will have one
hour rated walls.
5003.9 General safety precautions. General precautions for the safe storage, handling or care of
hazardous materials shall be in accordance with Sections 5003.9.1 through 5003.9.10.
5003.9.1 Personnel training and written procedures. Persons responsible for the
operation of areas in which hazardous materials are stored, dispensed, handled or
used shall be familiar with the chemical nature of the materials and the appropriate
mitigating actions necessary in the event of fire, leak or spill.
5003.9.1.1 Fire department liaison. Responsible persons shall be designated
and trained to be liaison personnel to the fire department. These persons shall
aid the fire department in preplanning emergency responses and identifying
the locations where hazardous materials are located, and shall have access to
Safety Data Sheets and be knowledgeable in the site’s emergency response
procedures.
5003.9.2 Security. Storage, dispensing, use and handling areas shall be
secured against unauthorized entry and safeguarded in a manner approved
by the fire code official.
5003.9.3 Protection from vehicles. Guard posts or other approved means shall be
provided to protect storage tanks and connected piping, valves and fittings;
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dispensing areas; and use areas subject to vehicular damage in accordance with
Section 312.
5003.9.4 Electrical wiring and equipment. Electrical wiring and equipment shall be
installed and maintained in accordance with NFPA 70.
5003.9.5 Static accumulation. Where processes or condition exist where a flammable
mixture could be ignited by static electricity, means shall be provided to prevent the
accumulation of a static charge.
5003.9.6 Protection from light. Materials that are sensitive to light shall be stored in
containers designed to protect them from such exposure.
5003.9.7 Shock padding. Materials that are shock sensitive shall be padded,
suspended or otherwise protected against accidental dislodgement and dislodgement
during seismic activity.
5003.9.8 Separation of incompatible materials. Incompatible materials in storage
and storage of materials that are incompatible with materials in use shall be
separated where the stored materials are in containers having a capacity of more
than 5 pounds, 0.5 gallon or any amount of compressed gases. Separation shall be
accomplished by:
1. Segregating incompatible materials in storage by distance of not less than 20’-0.
2. Isolating incompatible materials in storage by a noncombustible partition
extending not less than 18 inches above and to the sides of the stored material.
3. Storing liquid and solid materials in hazardous material storage cabinets.
4. Storing compressed gases in gas cabinets or exhausted enclosures in accordance
with Sections 5003.8.5 and 5003.8.6. Materials that are incompatible shall not be
stored within the same cabinet or exhausted enclosure.
5003.9.9 Shelf storage. Shelving shall be of substantial construction, and shall be
braced and anchored in accordance with the seismic design requirements of the
International Building Code for the seismic zone in which the material is located.
Shelving shall be treated, coated or constructed of materials that are compatible with
the hazardous materials stored. Shelves shall be provided with a lip or guard where
used for the storage of individual containers. Shelf storage of hazardous materials
shall be maintained in an orderly manner.
Exceptions:
1. Storage in hazardous material storage cabinets or laboratory furniture
specifically designed for such use.
2. Storage of hazardous materials in amounts not requiring a permit in
accordance with Section 5001.5.
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5003.9.10 Safety cans. Safety cans shall be listed in accordance with UL 30 where
used to increase the maximum allowable quantities per control area of flammable or
combustible liquids in accordance with Table 5003.1.1(1). Safety cans listed in
accordance with UL 1313 are allowed for flammable and combustible liquids where
not used to increase the maximum allowable quantities per control area and for other
hazardous material liquids in accordance with the listing. FM approved safety cans
will be used.
5003.10 Handling and transportation. In addition to the requirements of Section 5003.2,
the handling and transportation of hazardous materials in corridors or enclosures for
stairways and ramps shall be in accordance with Sections 5003.10.1 through 5003.10.3.6.
The hazardous materials will not be transported in corridors, enclosures for stairways
or ramps and therefore does not need to comply with Sections 5003.10.1 through
5003.10.3.6
The Storge and Use of Class IB flammable liquids shall also meet the requirements of Chapter 57 of
the 2020 Minnesota State Fire Code.
2020 MINNESOTA STATE FIRE CODE CHAPTER 57
5701 General
5701.1 Scope and application. Prevention, control and mitigation of dangerous conditions related to
storage, use, dispensing, mixing and handling of flammable and combustible liquids shall be in
accordance with Chapter 50 and this chapter.
5703 General Requirements
5703.1 Electrical. Electrical wiring and equipment shall be installed and maintained in accordance with
Section 605 and NFPA 70.
5703.1.1 Classified locations for flammable liquids. Areas where flammable liquids are
stored, handled, dispensed or mixed shall be in accordance with Table 5703.1.1. A classified
area shall not extend beyond an unpierced floor, roof or other solid partition.
The extent of the classified area is allowed to be reduced, or eliminated, where sufficient
technical justification is provided to the fire code official that a concentration in the area in
excess of 25 percent of the lower flammable limit (LFL) cannot be generated.
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5703.1.2 Classified locations for combustible liquids. Areas where Class II or III liquids are
heated above their flash points shall have electrical installations in accordance with Section
5703.1.1. N/A
5703.1.3 Other applications. The fire code official is authorized to determine the extent of
the Class I electrical equipment and wiring location when a condition is not specifically
covered by these requirements or NFPA 70.
5703.2 Fire protection. Fire protection for the storage, use, dispensing, mixing, handling and on-site
transportation of flammable and combustible liquids shall be in accordance with this chapter and
applicable sections of Chapter 9.
5703.2.1 Portable fire extinguishers and hose lines. Portable fire extinguishers shall be
provided in accordance with Section 906. Hose lines shall be provided in accordance with
Section 905.
906.3.2 Class B fire hazards. Portable fire extinguishers for occupancies involving
flammable or combustible liquids with depths of less than or equal to 0.25-inch shall
be selected and placed in accordance with Table 906.3(2).
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Portable fire extinguishers for occupancies involving flammable or combustible liquids
with a depth of greater than 0.25-inch shall be selected and placed in accordance with
NFPA 10.
NFPA 10
6.1.3 Placement.
6.1.3.1 Fire extinguishers shall be conspicuously located where they are
readily accessible and immediately available in the event of fire.
6.1.3.2 Fire extinguishers shall be located along normal paths of travel,
including exits from areas.
6.1.3.3 Visual Obstructions.
6.1.3.3.1 Fire extinguishers shall not be obstructed or obscured from
view.
6.1.3.8 Installation Height.
6.1.3.8.1 Fire extinguishers having a gross weight not exceeding 40 lb
shall be installed so that the top of the fire extinguisher is not more
than 5 ft above the floor.
6.1.3.8.2 Fire extinguishers having a gross weight greater than 40 lb
(except wheeled types) shall be installed so that the top of the fire
extinguisher is not more than 3-1⁄2 ft above the floor.
6.1.3.8.3 In no case shall the clearance between the bottom of the
hand portable fire extinguisher and the floor be less than 4 in.
6.1.3.4* Portable fire extinguishers other than wheeled extinguishers
shall be installed using any of the following means:
(1) Securely on a hanger intended for the extinguisher
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(2) In the bracket supplied by the extinguisher manufacturer
(3) In a listed bracket approved for such purpose
(4) In cabinets or wall recesses
6.1.3.5 Wheeled fire extinguishers shall be located in designated
locations. N/A
6.1.3.6 Fire extinguishers installed in vehicles or under other conditions
where they are subject to dislodgement shall be installed in approved
strap-type brackets specifically designed for this application. N/A
6.1.3.7 Fire extinguishers installed under conditions where they are
subject to physical damage (e.g., from impact, vibration, the
environment) shall be protected against damage.
6.3.2 Flammable Liquids of Appreciable Depth.
6.3.2.1 Portable fire extinguishers shall not be installed as the sole protection
for flammable liquid hazards of appreciable depth where the surface area
exceeds 10 ft2.
6.3.2.2* Where personnel who are trained in extinguishing fires in the
protected hazards are located on the premises and capable of responding
immediately, the maximum surface area shall not exceed 20 ft2.
6.3.2.3 For flammable liquid hazards of appreciable depth, a Class B fire
extinguisher shall be provided on the basis of at least 2 numerical units of
Class B extinguishing potential per 1 ft2 of flammable liquid surface of the
largest hazard area. Class B dry chemical fire extinguishers shall be provided.
6.3.2.4 AFFF- or FFFP-type fire extinguishers shall be permitted to be provided
on the basis of 1-B of protection per 1 ft2 of hazard. (For fires involving water-
soluble flammable liquids, see 5.5.3.) The stored liquids are water-soluble.
5.5.3 Water-Soluble Flammable Liquid Fires (Polar Solvents). Aqueous
film-forming foam (AFFF) and film-forming fluoroprotein foam (FFFP)
types of fire extinguishers shall not be used for the protection of
water-soluble flammable liquids, such as alcohols, acetone, esters,
ketones, and so forth, unless specifically referenced on the fire
extinguisher nameplate.
6.3.2.5 Two or more fire extinguishers of lower ratings, other than AFFF- or
FFFP-type fire extinguishers, shall not be used in lieu of the fire extinguisher
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required for the largest hazard area. N/A, the stored liquids are water-
soluble.
6.3.2.6 Up to three AFFF- or FFFP-type fire extinguishers shall be permitted to
fulfill the requirements, provided the sum of the Class B ratings meets or
exceeds the value required for the largest hazard area. N/A, the stored liquids
are water-soluble.
6.3.2.7 Travel distances for portable fire extinguishers shall not exceed 50 ft.
6.3.2.7.1 Scattered or widely separated hazards shall be individually
protected.
6.3.2.7.2 A fire extinguisher in the proximity of a hazard shall be
located to be accessible in the presence of a fire without undue danger
to the operator.
5703.3 Site assessment. In the event of a spill, leak or discharge from a tank system, a site
assessment shall be completed by the owner or operator of such tank system if the fire code official
determines that a potential fire or explosion hazard exists. Such site assessments shall be conducted
to ascertain potential fire hazards and shall be completed and submitted to the fire department
within a time period established by the fire code official, not to exceed 60 days.
5703.4 Spill control and secondary containment. Where the maximum allowable quantity per
control area is exceeded, and when required by Section 5004.2, rooms, buildings or areas used for
storage, dispensing, use, mixing or handling of Class I, II and IIIA liquids shall be provided with spill
control and secondary containment in accordance with Section 5004.2.
5703.5 Labeling and signage. The fire code official is authorized to require warning signs for the
purpose of identifying the hazards of storing or using flammable liquids. Signage for identification
and warning such as for the inherent hazard of flammable liquids or smoking shall be provided in
accordance with this chapter and Sections 5003.5 and 5003.6. Warning signs are required.
5703.5.1 Style. Warning signs shall be of a durable material. Signs warning of the hazard of
flammable liquids shall have white lettering on a red background and shall read: DANGER—
FLAMMABLE LIQUIDS. Letters shall not be less than 3 inches in height and 1/2 inch in stroke.
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5703.5.2 Location. Signs shall be posted in locations as required by the fire code official.
Piping containing flammable liquids shall be identified in accordance with ASME A13.1.
5703.5.3 Warning labels. Individual containers, packages and cartons shall be identified,
marked, labeled and placarded in accordance with federal regulations and applicable state
laws.
5703.5.4 Identification. Color coding or other approved identification means shall be
provided on each loading and unloading riser for flammable or combustible liquids to identify
the contents of the tank served by the riser.
5704 Storage
5704.1. General. The storage of flammable and combustible liquids in containers shall be IAW this
section and Chapter 50.
5704.1.1 Application of sprinkler protection tables. Tables 5704.3.6.3(4) through
5704.3.6.3(8) shall only apply to liquids stored in metal containers and tanks. For liquids
stored in nonmetallic containers, nonmetallic portable tanks or rigid nonmetallic
intermediate bulk containers, sprinkler protection shall be designed and installed in
accordance with criteria based on full-scale fire testing conducted at an approved testing
laboratory or based on other nationally recognized fire safety standards approved by the
code official.
The Class 1B liquid Isopropyl alcohol will be stored in metal 55-gallon drums and the Class
IB Methanol and Acetone will be stored in 1-gallon glass bottles.
5704.3. Container and portable tank storage. Storage of flammable and combustible liquids in
closed containers that do not exceed 60 gallons in individual capacity shall comply with section
5704.3.1 through 5704.3.8.5
5704.3.1 Design Construction and capacity of containers and portable tanks. The design
and construction and capacity of containers for the storage of Class I, II, and IIIA liquids shall
be in accordance with this section and NFPA 30 Section 9.4.
2015 NFPA 30
9.4 Acceptable Containers.
9.4.1* Only the following approved containers, intermediate bulk containers, and
portable tanks shall be used for Class I, Class II, and Class IIIA liquids:
(1) Metal containers, metal intermediate bulk containers, and metal portable tanks
meeting the requirements of and containing products authorized by the U.S.
17
Department of Transportation Hazardous Materials Regulations in Title 49, Code of
Federal Regulations, Parts 100–199, or by Part 6 of the UN Recommendations on the
Transport of Dangerous Goods.
Isopropyl Alcohol will be stored in metal 55-gallon drums.
(3) Nonmetallic or metallic commercial/industrial safety cans meeting the
requirements of, and used within the scope of, one or more of the following
specifications:
(a) ANSI/UL 30, Standard for Metal Safety Cans
(b) ANSI/UL 1313, Standard for Nonmetallic Safety Cans for Petroleum
Products
(c) FM Global Approval Standard for Safety Containers and Filling, Supply, and
Disposal Containers — Class Number 6051 and 6052
The 5-gallon safety lab cans currently used in the facility are FM approved.
(7) Glass containers up to the capacity limits stated in Table 9.4.3 and in accordance
with U.S. Department of Transportation Hazardous Materials Regulations in Title 49,
Code of Federal Regulations, Parts 100–199. Methanol and Acetone will be stored in
1 gallon glass containers in cartons.
5704.3.1.1 Approved containers. Only approved containers shall be used.
5704.3.2 Liquid Storage Cabinets. Where other sections of this code require that liquid
containers be stored in storage cabinets, such cabinets and storage shall be in accordance
with Sections 5704.3.2.1 through 5704.3.2.2. The storage cabinets in this facility will be
approved for the storage of flammable liquids.
5704.3.2.1 Design and construction of storage cabinets. Design and construction of liquid
storage cabinets shall be in accordance with Sections 5704.3.2.1 through 5704.3.2.1.4.
5704.3.2.1.1 Materials. Cabinets shall be listed in accordance with UL 1275.
18
5704.3.2.1.2 Labeling. Cabinets shall be provided with a conspicuous label in red letters on
contrasting background that reads: FLAMMABLE—KEEP FIRE AWAY.
5704.3.2.1.3 Doors. Doors shall be well fitted, self-closing and equipped with a three-point
latch.
5704.3.2.1.4 Bottom. The bottom of the cabinet shall be liquid tight to a height of not less
than 2 inches.
5704.3.2.2 Capacity. The combined total quantity of liquids in a cabinet shall not exceed 120
gallons.
5704.3.3 Indoor storage. Storage of flammable and combustible liquids inside buildings in
containers shall be in accordance with sections 5704.3.3.1 through 5704.3.3.11.
5704.3.3.1 Portable fire extinguishers. Approved portable fire extinguishers shall be
provided in accordance with specific sections of this chapter and Section 906.
5704.3.3.2 Incompatible materials. Materials that will react with water or other liquids to
produce a hazard shall not be stored in the same room with flammable and combustible
liquids in accordance with Section 5003.9.8.
5704.3.3.3 Clear means of egress. Storage of any liquids, including stock for sale, shall not be
stored near or be allowed to obstruct physically the route of egress.
5704.3.3.4 Empty containers or portable tank storage. The storage of empty tanks and
containers previously used for the storage of flammable or combustible liquids, unless free
from explosive vapors, shall be stored as required for filled containers and portable tanks.
Portable tanks and containers, when emptied, shall have the covers or plugs immediately
replaced in openings.
5704.3.3.5 Shelf storage. Shelving shall be of approved construction, adequately braced and
anchored. Seismic requirements shall be in accordance with the International Building Code.
5704.3.3.6 Rack storage. Where storage on racks is allowed elsewhere in this code, a
minimum 4-foot-wide aisle shall be provided between adjacent rack sections and any
adjacent storage of liquids. Main aisles shall be a minimum of 8 feet wide. N/A
5704.3.3.7 Pile or palletized storage. Solid pile and palletized storage in liquid warehouses
shall be arranged so that piles are separated from each other by at least 4 feet. Aisles shall be
provided and arranged so that no container or portable tank is more than 20 feet from an
aisle. Main aisles shall be a minimum of 8 feet wide. N/A
5704.3.3.8 Limited combustible storage. Limited quantities of combustible commodities are
allowed to be stored in liquid storage areas where the ordinary combustibles, other than
19
those used for packaging the liquids, are separated from the liquids in storage by a minimum
of 8 feet horizontally, either by open aisles or by open racks, and where protection is
provided in accordance with Chapter 9.
5704.3.3.9 Idle combustible pallets. Storage of empty or idle combustible pallets inside an
unprotected liquid storage area shall be limited to a maximum pile size of 2,500 square feet
and to a maximum storage height of 6 feet. Storage of empty or idle combustible pallets
inside a protected liquid storage area shall comply with NFPA 13. Pallet storage shall be
separated from liquid storage by aisles that are at least 8 feet wide.
5704.3.3.10 Containers in piles. Containers in piles shall be stacked in such a manner as to
provide stability and to prevent excessive stress on container walls. Portable tanks stored
more than one tier high shall be designed to nest securely, without dunnage. Material
handling equipment shall be suitable to handle containers and tanks safely at the upper tier
level.
5704.3.3.11 Fire-extinguishing systems. Automatic sprinkler and foam-water systems
provided for the protection of container, intermediate bulk container and portable tank
storage shall be of the wet pipe, deluge or pre-action type. If pre-action systems are used,
they shall be designed so that water or foam solution discharges immediately from the
sprinkler opened by heat from a fire.
5704.3.4 Quantity limits for storage. Liquid storage quantity limitations shall comply with Sections
5704.3.4.1 through 5704.3.4.4.
5704.3.4.1 Maximum allowable quantity per control area. For occupancies other than
Group M wholesale and retail sales uses, indoor storage of flammable and combustible
liquids shall not exceed the maximum allowable quantities per control area indicated in Table
5003.1.1(1) and shall not exceed the additional limitations set forth in this section.
5704.3.4.3 Quantities exceeding limits for control areas. Quantities exceeding those allowed
in control areas set forth in Section 5704.3.4.1 shall be in liquid storage rooms or liquid
storage warehouses in accordance with Sections 5704.3.7 and 5704.3.8.
The quantities of Class IB liquids to be stored and “in use” exceed the MAQs in Table
5003.1.1(1) and therefore shall be stored in a liquid storage room in accordance with
Section 5704.3.7.
5704.3.7 Liquid storage rooms. Liquid storage rooms shall comply with Sections 5704.3.7.1 through
5704.3.7.5.2.
5704.3.7.1 General. Quantities of liquids exceeding those set forth in Section 5704.3.4.1 for
storage in control areas shall be stored in a liquid storage room complying with this section
and constructed and separated as required by the International Building Code.
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2020 MN State Building Code
415.11.5 HPM rooms, gas rooms, liquid storage room construction. HPM
rooms, gas rooms and liquid storage rooms shall be constructed in accordance
with Sections 415.11.5.1 through 415.11.5.9.
[F] 415.11.5.2 Liquid storage rooms. Liquid storage rooms shall be
constructed in accordance with the following requirements:
1. Rooms greater than 500 square feet in area, shall have no fewer
than one exterior door approved for fire department access. The room
is 124 sqft and therefore an exterior door is not required.
2. Rooms shall be separated from other areas by fire barrier
constructed in accordance with Section 707 or horizontal assemblies
constructed in accordance with Section 711, or both. The fire
resistance rating shall be not less than 1 hour for rooms up to 150
square feet in area and not less than 2 hours where the room is more
than 150 square feet in area. 1-hour walls shall be provided for liquid
storage rooms of 150 sqft or less. The area of the Liquid storage room
is approximately 124 sqft therefore 1-hour walls shall be provided.
3. Shelving, racks and wainscotting in such areas shall be of
noncombustible construction or wood of not less than 1-inch nominal
thickness or fire-retardant-treated wood complying with Section
2303.2. Shelving, racks and wainscoting shall be noncombustible.
4. Rooms used for the storage of Class I flammable liquids shall not be
located in a basement. N/A
[F] 415.11.5.3 Floors. Except for surfacing, floors of HPM rooms and
liquid storage rooms shall be of noncombustible liquid-tight
construction. Raised grating over floors shall be of noncombustible
materials. Liquid Storage Room floor shall be of noncombustible
liquid tight construction.
[F] 415.11.5.4 Location. Where HPM rooms, liquid storage rooms and
gas rooms are provided, they shall have no fewer than one exterior
wall and such wall shall be not less than 30 feet from lot lines,
including lot lines adjacent to public ways.
As this is an unlimited area building, Section 507.8 also applies which
does not require the room to be located on the outer perimeter if the
room is less than 1000 sqft.
21
[F] 415.11.5.5 Explosion control. Explosion control shall be provided
where required by Section 414.5.1.
[F] 414.5.1 Explosion control. Explosion control shall be
provided in accordance with the International Fire Code as
required by Table 414.5.1 where quantities of hazardous
materials specified in that table exceed the maximum allowable
quantities in Table 307.1(1) or where a structure, room or
space is occupied for purposes involving explosion hazards as
required by Section 415 or the International Fire Code.
Explosion control is not required IAW Table 414.5.1 as the
MAQs in open use or dispensing are not exceeded.
[F] 415.11.5.6 Exits. Where two exits are required from HPM rooms,
liquid storage rooms and gas rooms, one shall be directly to the
outside of the building. Only one exit is required.
[F] 415.11.5.7 Doors. Doors in a fire barrier wall, including doors to
corridors, shall be self-closing fire door assemblies having a fire
protection rating of not less than 3/4 hour. Doors shall be self-closing
fire door assemblies of not less than ¾ hour for 1 hour walls.
22
[F] 415.11.5.8 Ventilation. Mechanical exhaust ventilation shall be
provided in liquid storage rooms, HPM rooms and gas rooms at the
rate of not less than 1 cubic foot per minute per square foot of floor
area or six air changes per hour, whichever is greater, for categories of
material. Mechanical Exhaust Ventilation shall be provided for the
Liquid Storage Room
[F] 415.11.5.9 Emergency alarm system. An approved emergency
alarm system shall be provided for HPM rooms, liquid storage rooms
and gas rooms. An Emergency Alarm System shall be provided for the
liquid storage room IAW with below requirements.
Emergency alarm-initiating devices shall be installed outside of each
interior exit door of such rooms.
Activation of an emergency alarm-initiating device shall sound a local
alarm and transmit a signal to the emergency control station.
An approved emergency telephone system, local alarm manual pull
stations or other approved alarm-initiating devices are allowed to be
used as emergency alarm-initiating devices.
507.8 Group H-2, H-3 and H-4 occupancies. Group H-2, H-3 and H-4 occupancies shall
be permitted in unlimited area buildings containing Group F or S occupancies in
accordance with Sections 507.4 and 507.5 and the provisions of Sections 507.8.1
through 507.8.4.
507.8.1 Allowable area. The aggregate floor area of Group H occupancies
located in an unlimited area building shall not exceed 10 percent of the area
of the building or the area limitations for the Group H occupancies as specified
in Section 506 based on the perimeter of each Group H floor area that fronts
on a public way or open space. The aggregate area of all H occupancies shall
not exceed 8,750 ft2
507.8.1.1 Located within the building. The aggregate floor area of
Group H occupancies not located at the perimeter of the building shall
not exceed 25 percent of the area limitations for the Group H
occupancies as specified in Section 506.
507.8.1.1.1 Liquid use, dispensing and mixing rooms. Liquid
use, dispensing and mixing rooms having a floor area of not
more than 500 square feet need not be located on the outer
23
perimeter of the building where they are in accordance with
the International Fire Code and NFPA 30.
507.8.1.1.2 Liquid storage rooms. Liquid storage rooms having
a floor area of not more than 1,000 square feet need not be
located on the outer perimeter where they are in accordance
with the International Fire Code and NFPA 30. The liquid
storage room is not required to be located on the outer
perimeter as the area of the room is only 124 ft2
507.8.1.1.3 Spray paint booths. Spray paint booths that comply
with the International Fire Code need not be located on the
outer perimeter. N/A
5704.3.7.2 Quantities and arrangement of storage. The quantity limits and storage
arrangements in liquid storage rooms shall be in accordance with Tables 5704.3.6.3(2) and
5704.3.6.3(3) and Sections 5704.3.7.2.1 through 5704.3.7.2.
The maximum quantity of Class IB liquids stored in a liquid storage room is 1 drum, 6.5 feet
high, maximum of 5,000 gallons per pile and a maximum of 15,000 gallons per room IAW
Table 5704.3.6.3(2).
24
5704.3.7.2.1 Mixed storage. Where two or more classes of liquids are stored in a pile
or rack section: N/A
5704.3.7.2.2 Separation and aisles. Piles shall be separated from each other by at
least 4-foot aisles. Aisles shall be provided so that all containers are 20 feet or less
from an aisle. Where the storage of liquids is on racks, a minimum 4-foot-wide aisle
shall be provided between adjacent rows of racks and adjacent storage of liquids.
Main aisles shall be a minimum of 8 feet wide.
Additional aisles shall be provided for access to doors, required windows and
ventilation openings, standpipe connections, mechanical equipment and switches.
Such aisles shall be at least 3 feet in width, unless greater widths are required for
separation of piles or racks, in which case the greater width shall be provided.
5704.3.7.2.3 Stabilizing and supports. Containers and piles shall be separated by
pallets or dunnage to provide stability and to prevent excessive stress to container
walls. Portable tanks stored over one tier shall be designed to nest securely without
dunnage.
Requirements for portable tank design shall be in accordance with Chapters 9 and 12
of NFPA 30. Shelving, racks, dunnage, scuffboards, floor overlay and similar
installations shall be of noncombustible construction or of wood not less than a 1-
inch (25 mm) nominal thickness. Adequate material-handling equipment shall be
available to handle tanks safely at upper tier levels.
5704.3.7.3 Spill control and secondary containment. Liquid storage rooms shall be provided
with spill control and secondary containment in accordance with Section 5004.2.
5004.2 Spill control and secondary containment for liquid and solid hazardous
materials. Rooms, buildings or areas used for the storage of liquid or solid
hazardous materials shall be provided with spill control and secondary
containment in accordance with Sections 5004.2.1 through 5004.2.3.
5004.2.1 Spill control for hazardous material liquids. Rooms, buildings or
areas used for the storage of hazardous material liquids in individual vessels
having a capacity of more than 55 gallons, or in which the aggregate capacity
of multiple vessels exceeds 1,000 gallons, shall be provided with spill control to
prevent the flow of liquids to adjoining areas. Floors in indoor locations and
similar surfaces in outdoor locations shall be constructed to contain a spill
from the largest single vessel by one of the following methods:
1. Liquid-tight sloped or recessed floors in indoor locations or similar
areas in outdoor locations.
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2. Liquid-tight floors in indoor locations or similar areas in outdoor
locations provided with liquid-tight raised or recessed sills or dikes.
3. Sumps and collection systems.
4. Other approved engineered systems.
The liquid storage room shall be of noncombustible liquid tight construction
IAW MN State Building Code.
Except for surfacing, the floors, sills, dikes, sumps and collection systems shall
be constructed of noncombustible material, and the liquid-tight seal shall be
compatible with the material stored. When liquid-tight sills or dikes are
provided, they are not required at perimeter openings having an open-grate
trench across the opening that connects to an approved collection system.
5004.2.2 Secondary containment for hazardous material liquids and solids.
Where required by Table 5004.2.2 buildings, rooms or areas used for the
storage of hazardous materials liquids or solids shall be provided with
secondary containment in accordance with this section when the capacity of
an individual vessel or the aggregate capacity of multiple vessels exceeds the
following:
1. Liquids: Capacity of an individual vessel exceeds 55 gallons or the
aggregate capacity of multiple vessels exceeds 1,000 gallons.
The quantity of Class IB liquids does not exceed 1000 gallons and the largest
vessel is 55 gallons and therefore secondary containment is not required for
the liquid storage room.
26
5704.3.7.4 Ventilation. Liquid storage rooms shall be ventilated in accordance with Section
5004.3.
5004.3 Ventilation. Indoor storage areas and storage buildings shall be
provided with mechanical exhaust ventilation or natural ventilation where
natural ventilation can be shown to be acceptable for the materials as stored.
Mechanical ventilation shall be provided to meet the requirements below.
5004.3.1 System requirements. Exhaust ventilation systems shall
comply with all of the following:
1. Installation shall be in accordance with the International
Mechanical Code.
2. Mechanical ventilation shall be at a rate of not less than 1
cubic foot per minute per square foot of floor area over the
storage area.
3. Systems shall operate continuously unless alternative designs
are approved.
4. A manual shutoff control shall be provided outside of the
room in a position adjacent to the access door to the room or in
an approved location. The switch shall be a break-glass or other
approved type and shall be labeled: VENTILATION SYSTEM
EMERGENCY SHUTOFF.
5. Exhaust ventilation shall be designed to consider the density
of the potential fumes or vapors released. For fumes or vapors
that are heavier than air, exhaust shall be taken from a point
within 12 inches of the floor. For fumes or vapors that are lighter
than air, exhaust shall be taken from a point within 12 inches of
the highest point of the room.
6. The location of both the exhaust and inlet air openings shall
be designed to provide air movement across all portions of the
floor or room to prevent the accumulation of vapors.
7. Exhaust air shall not be recirculated to occupied areas if the
materials stored are capable of emitting hazardous vapors and
contaminants have not been removed. Air contaminated with
explosive or flammable vapors, fumes or dusts; flammable,
highly toxic or toxic gases; or radioactive materials shall not be
recirculated.
5704.3.7.5 Fire protection. Fire protection for liquid storage rooms shall comply with
Sections 5704.3.7.5.1 and 5704.3.7.5.2.
27
5704.3.7.5.1 Fire-extinguishing systems. Liquid storage rooms shall be protected by
automatic sprinkler systems installed in accordance with Chapter 9 and Tables
5704.3.6.3(4) through 5704.3.6.3(7) and Table 5704.3.7.5.1. In-rack sprinklers shall
also comply with NFPA 13.
The Class IB liquids (Isopropyl Alcohol) in metal 55 gallon drums will be stored one
high in the liquid storage room. The liquid storage room shall be protected with an
Automatic Sprinkler System with a design density of 0.25/5,000 sqft with high
temperature sprinklers. The maximum spacing shall not exceed 100 sqft. A hose
demand of 500 gpm shall be added.
Protection criteria developed from fire modeling or full-scale fire testing conducted at
an approved testing laboratory are allowed in lieu of the protection as shown in
Tables 5704.3.6.3(2) through 5704.3.6.3(7) and Table 5704.3.7.5.1 where approved.
Protection of Class IB liquid, Methanol and Acetone, in one gallon glass containers is
not addressed in NFPA 13. FM Global Data Sheet 07-29 will be referenced for
protection criteria.
2.4.5 Protection of Plastic, Composite (Plastic-Metal), or Other Combustible
Containers: General
2.4.5.1 Protect storage of all ignitable liquids in plastic, composite (plastic-
metal), glass, or other combustible packaging in accordance with Table
2.4.5.1. See Section 3.5.5 for more information.
2.4.5.2 Protect ignitable liquids in plastic or glass containers stored in shelves
using the criteria in Table 2.4.5.1.
28
The Class IB liquids, Methanol and Acetone, in glass 1 gallon bottles will be stored in
cartons palletized or on shelves in the liquid storage room to a maximum storage
height of 5 feet. The liquid storage room shall be protected with an Automatic
Sprinkler System IAW Table 2.4.5.1 above using Standard Response sprinklers. The
maximum spacing shall not exceed 100 sqft. A hose demand of 500 gpm shall be
added.
5704.3.7.5.2 Portable fire extinguishers. A minimum of one approved portable fire
extinguisher complying with Section 906 and having a rating of not less than 20-B
shall be located not less than 10 feet or more than 50 feet from any Class I or II liquid
storage area located outside of a liquid storage room. Provide Fire Extinguishers as
described above.
5704.4 Outdoor storage of containers and portable tanks. Storage of flammable and combustible
liquids in closed containers and portable tanks outside of buildings shall be in accordance with
Section 5703 and Sections 5704.4.1 through 5704.4.8. Capacity limits for containers and portable
tanks shall be in accordance with Section 5704.3.
5704.4.1 Plans. Storage shall be in accordance with approved plans.
5704.4.2 Location on property. Outdoor storage of liquids in containers and portable tanks
shall be in accordance with Table 5704.4.2. Storage of liquids near buildings located on the
same lot shall be in accordance with this section.
29
The storage of containers outdoors in piles must not exceed 2200 gallons and 12’-0 in
height per pile. The minimum distance between piles shall be 5 feet.
The minimum distance to lot line of property that can be built on is 50’-0. The minimum
distance to a public street, public alley or public way is 10 feet. The above distances can be
reduced by 50% if the quantity stored does not exceed 50% of the maximum quantity per
pile.
5704.4.2.1 Mixed liquid piles. Where two or more classes of liquids are stored in a
single pile, the quantity in the pile shall not exceed the smallest of maximum
quantities for the classes of material stored. N/A
5704.4.2.2 Access. Storage of containers or portable tanks shall be provided with fire
apparatus access roads in accordance with Chapter 5.
5704.4.2.3 Security. The storage area shall be protected against tampering or
trespassers where necessary and shall be kept free from weeds, debris and other
combustible materials not necessary to the storage.
5704.4.2.4 Storage adjacent to buildings. Not more than 1,100 gallons of liquids
stored in closed containers and portable tanks is allowed adjacent to a building
located on the same premises and under the same management, provided that one
of the following requirements is met:
1. The building does not exceed one story in height. Such building shall be of
fire-resistance-rated construction with noncombustible exterior surfaces or
noncombustible construction and shall be used principally for the storage of
liquids.
2. The exterior building wall adjacent to the storage area shall have a fire-
resistance rating of not less than 2 hours, having no openings to above-grade
areas within 10 feet horizontally of such storage and no openings to below-
grade areas within 50 feet horizontally of such storage.
30
The quantity of liquids stored adjacent to a building protected in accordance
with Item 2 is allowed to exceed 1,100 gallons, provided that the maximum
quantity per pile does not exceed 1,100 gallons and each pile is separated by a
10-foot-minimum clear space along the common wall.
Where the quantity stored exceeds 1,100 gallons adjacent to a building
complying with Item 1, or the provisions of Item 1 cannot be met, a minimum
distance in accordance with Table 5704.4.2, column 7 (“Minimum Distance to
Lot Line of Property That Can Be Built Upon”) shall be maintained between
buildings and the nearest container or portable tank.
5704.4.3 Spill control and secondary containment. Storage areas shall be provided with spill
control and secondary containment in accordance with Section 5703.4.
Exception: Containers stored on approved containment pallets in accordance with
Section 5004.2.3 and containers stored in cabinets and lockers with integral spill
containment.
5704.4.4 Security. Storage areas shall be protected against tampering or trespassers by
fencing or other approved control measures.
5704.4.5 Protection from vehicles. Guard posts or other means shall be provided to protect
exterior storage tanks from vehicular damage. Where guard posts are installed, the posts
shall be installed in accordance with Section 312.
SECTION 312 VEHICLE IMPACT PROTECTION
312.1 General. Vehicle impact protection required by this code shall be
provided by posts that comply with Section 312.2 or by other approved
physical barriers that comply with Section 312.3.
312.2 Posts. Guard posts shall comply with all of the following requirements:
31
1. Constructed of steel not less than 4 inches in diameter and
concrete filled.
2. Spaced not more than 4 feet between posts on center.
3. Set not less than 3 feet deep in a concrete footing of not less than
a 15-inch diameter.
4. Set with the top of the posts not less than 3 feet above ground.
5. Located not less than 3 feet from the protected object.
312.3 Other barriers. Barriers, other than posts specified in Section 312.2,
that are designed to resist, deflect or visually deter vehicular impact
commensurate with an anticipated impact scenario shall be permitted
where approved.
5704.4.6 Clearance from combustibles. The storage area shall be kept free from weeds,
debris and combustible materials not necessary to the storage. The area surrounding an
exterior storage area shall be kept clear of such materials for a minimum distance of 15
feet.
5704.4.7 Weather protection. Weather protection for outdoor storage shall be in
accordance with Section 5004.13.
5004.13 Weather protection. Where overhead noncombustible construction is
provided for sheltering outdoor hazardous material storage areas, such storage
shall not be considered indoor storage where the area is constructed in accordance
with the requirements for weather protection as required by the International
Building Code.
5704.4.8 Empty containers and tank storage. The storage of empty tanks and containers
previously used for the storage of flammable or combustible liquids, unless free from
explosive vapors, shall be stored as required for filled containers and tanks. Tanks and
containers when emptied shall have the covers or plugs immediately replaced in openings.
SECTION 5705 DISPENSING, USE, MIXING AND HANDLING
5705.1 Scope. Dispensing, use, mixing and handling of flammable liquids shall be in accordance
with Section 5703 and this section. Tank vehicle and tank car loading and unloading and other
special operations shall be in accordance with Section 5706.
5705.2 Liquid transfer. Liquid transfer equipment and methods for transfer of Class I, II and IIIA
liquids shall be approved and be in accordance with Sections 5705.2.1 through 5705.2.6.
32
5705.2.1 Pumps. Where positive-displacement pumps are used, they shall be provided with
pressure relief discharging back to the tank, pump suction or other approved location, or
shall be provided with interlocks to prevent overpressure.
5705.2.2 Pressured systems. Where gases are introduced to provide for transfer of Class I
liquids, or Class II and III liquids transferred at temperatures at or above their flash points by
pressure, only inert gases shall be used. Controls, including pressure relief devices, shall be
provided to limit the pressure so that the maximum working pressure of tanks, containers
and piping systems cannot be exceeded. Where devices operating through pressure within a
tank or container are used, the tank or container shall be a pressure vessel approved for the
intended use. Air or oxygen shall not be used for pressurization. Inert gas will be used.
5705.2.3 Piping, hoses and valves. Piping, hoses and valves used in liquid transfer operations
shall be approved or listed for the intended use. The piping, hoses and fittings will be listed
or approved.
5705.2.4 Class I, II and III liquids. Class I liquids or, when heated to or above their flash
points, Class II and Class III liquids, shall be transferred by one of the following methods:
1. From safety cans complying with UL 30.
2. Through an approved closed piping system.
3. From containers or tanks by an approved pump taking suction through an opening
in the top of the container or tank. This method will be used.
4. For Class IB, IC, II and III liquids, from containers or tanks by gravity through an
approved self-closing or automatic-closing valve where the container or tank and
dispensing operations are provided with spill control and secondary containment in
accordance with Section 5703.4. Class IA liquids shall not be dispensed by gravity
from tanks.
5. Approved engineered liquid transfer systems.
Exception: Liquids in original shipping containers not exceeding a 5.3-gallon
capacity.
5705.2.5 Manual container filling operations. Class I liquids or Class II and Class III liquids
that are heated up to or above their flash points shall not be transferred into containers
unless the nozzle and containers are electrically interconnected. Acceptable methods of
electrical interconnection include either of the following:
1. Metallic floor plates on which containers stand while filling, where such floor plates
are electrically connected to the fill stem.
2. Where the fill stem is bonded to the container during filling by means of a bond
wire.
The nozzle and containers will be electrically interconnected
33
5705.2.6 Automatic container-filling operations for Class I liquids. Container-filling
operations for Class I liquids involving conveyor belts or other automatic-feeding operations
shall be designed to prevent static accumulations. N/A
5705.3 Use, dispensing and mixing inside of buildings. Indoor use, dispensing and mixing of
flammable and combustible liquids shall be in accordance with Section 5705.2 and Sections 5705.3.1
through 5705.3.5.3.
5705.3.1 Closure of mixing or blending vessels. Vessels used for mixing or blending of Class I
liquids and Class II or III liquids heated up to or above their flash points shall be provided with
self-closing, tight-fitting, noncombustible lids that will control a fire within such vessel. N/A
5705.3.2 Bonding of vessels. Where differences of potential could be created, vessels
containing Class I liquids or liquids handled at or above their flash points shall be electrically
connected by bond wires, ground cables, piping or similar means to a static grounding
system to maintain equipment at the same electrical potential to prevent sparking.
5705.3.3 Heating, lighting and cooking appliances. Heating, lighting and cooking appliances
that utilize Class I liquids shall not be operated within a building or structure. N/A
5705.3.4 Location of processing vessels. Processing vessels shall be located with respect to
distances to lot lines of adjoining property that can be built on, in accordance with Tables
5705.3.4(1) and 5705.3.4(2). N/A
5705.3.5 Quantity limits for use. Liquid use quantity limitations shall comply with Sections
5705.3.5.1 through 5705.3.5.3.
5705.3.5.1 Maximum allowable quantity per control area. Indoor use, dispensing
and mixing of flammable and combustible liquids shall not exceed the maximum
allowable quantity per control area indicated in Table 5003.1.1(1) and shall not
exceed the additional limitations set forth in Section 5705.3.5. The indoor use and
dispensing of flammable liquids does not exceed the MAQs in Table 5003.1.1(1).
a. The MAQ of 120 gallons “in closed use” in the liquid storage room is not
exceeded as there will only be 110 gallons.
b. The MAQ of 60 gallons “in open use” in the warehouse area is not
exceeded as there will only be 60 gallons.
5705.3.5.3 Quantities exceeding limits for control areas. Quantities exceeding the
maximum allowable quantity per control area indicated in Sections 5705.3.5.1 and
5705.3.5.2 shall be in accordance with the following: N/A
34
5705.3.7 Rooms or buildings for quantities exceeding the maximum allowable quantity per
control area. Where required by Section 5705.3.5.3 or 5705.3.6.1, rooms or buildings used
for the use, dispensing or mixing of flammable and combustible liquids in quantities
exceeding the maximum allowable quantity per control area shall be in accordance with
Sections 5705.3.7.1 through 5705.3.7.6.3.
5705.3.7.1 Construction, location and fire protection. Rooms or buildings classified in
accordance with the International Building Code as Group H-2 or H-3 occupancies
based on use, dispensing or mixing of flammable or combustible liquids shall be
constructed in accordance with the International Building Code.
5705.3.7.2 Basements. In rooms or buildings classified in accordance with the
International Building Code as Group H-2 or H-3, dispensing or mixing of flammable or
combustible liquids shall not be conducted in basements. N/A
5705.3.7.3 Fire protection. Rooms or buildings classified in accordance with the
International Building Code as Group H-2 or H-3 occupancies shall be equipped with
an approved automatic fire-extinguishing system in accordance with Chapter 9.
5705.3.7.4 Doors. Interior doors to rooms or portions of such buildings shall be self-
closing fire doors in accordance with the International Building Code. The interior
door shall be self-closing.
5705.3.7.5 Open systems. Use, dispensing and mixing of flammable and combustible
liquids in open systems shall be in accordance with Sections 5705.3.7.5.1 through
5705.3.7.5.3. N/A
5705.3.7.5.1 Ventilation. Continuous mechanical ventilation shall be provided
at a rate of not less than 1 cfm per square foot [0.00508 m3/(s • m2)] of floor
area over the design area. Provisions shall be made for introduction of
makeup air in such a manner to include all floor areas or pits where vapors
can collect. Local or spot ventilation shall be provided where needed to
prevent the accumulation of hazardous vapors. Ventilation system design shall
comply with the International Building Code and International Mechanical
Code.
5705.3.7.6 Closed systems. Use or mixing of flammable or combustible liquids in
closed systems shall be in accordance with Sections 5705.3.7.6.1 through
5705.3.7.6.3.
5705.3.7.6.1 Ventilation. Closed systems designed to be opened as part of
normal operations shall be provided with ventilation in accordance with
Section 5705.3.7.5.1. Ventilation shall be provided IAW 5705.3.7.5.1
35
5705.3.7.6.2 Explosion control. Explosion control shall be provided where an
explosive environment can occur as a result of the mixing or use process.
Explosion control shall be designed in accordance with Section 911. N/A
5705.3.7.6.3 Spill control and secondary containment. Spill control shall be
provided in accordance with Section 5703.4 where flammable or combustible
liquids are dispensed into containers exceeding a 1.3-gallon capacity or mixed
or used in open containers or systems exceeding a 5.3-gallon capacity. Spill
control and secondary containment shall be provided in accordance with
Section 5703.4 where the capacity of an individual container exceeds 55
gallons or the aggregate capacity of multiple containers or tanks exceeds
1,000 gallons. Spill control shall be provided in the liquid storage room and
outside the storage room where flammable liquids are dispensed into
containers exceeding 1.3 gallons.
36
Conclusion
A. The Heraeus Medevio storage of Class IB Flammable Liquids in the Liquid Storage Room and
Warehouse Control Area will meet the code requirements of the 2020 Minnesota State Building
Code and 2020 Minnesota State Fire Code with the following provisions:
1) Provide warning signs and post in locations required by the fire code official.
2) Approved containers shall be used. (metal drums, 1 gallon glass bottles & FM approved safety cans)
3) One (1) hour walls shall be provided for the liquid storage room.
4) Doors for the liquid storage room shall be self-closing fire door assembly rated for 45-minutes.
5) Shelving in the liquid storage room shall be noncombustible, braced and anchored, and compatible
with the liquids being stored.
a. Storage shall only be one steel drum high
b. Storage shall be only up to 5 feet high for Methanol and acetone in the one-gallon glass
containers.
6) Floor shall be noncombustible liquid tight construction in the liquid storage room and where
dispensing will occur.
7) The liquid storage room and areas where flammable liquids will be used must be classified IAW
Table 5703.1.1.
* Industrial trucks will not be used in or within 5 feet of the new H-2 room.
8) Explosion Control is not required.
9) A minimum of 4’-0 aisles shall be provided in the liquid storage room.
10) Mechanical Exhaust ventilation shall be provided for the liquid storage room:
a. Ventilation shall be at a rate of not less than 1 cubic foot per minute per square foot of floor
area over the storage area.
b. System shall operate continuously.
c. A manual shutoff control shall be provided outside of the room in a position adjacent to the
access door to the room or in an approved location. The switch shall be a break-glass or
other approved type and shall be labeled: VENTILATION SYSTEM EMERGENCY SHUTOFF.
d. The location of both the exhaust and inlet air openings shall be designed to provide air
movement across all portions of the floor or room to prevent the accumulation of vapors.
e. Exhaust air shall not be recirculated to occupied areas if the materials stored are capable of
emitting hazardous vapors and contaminants have not been removed.
11) An approved emergency alarm system shall be provided for the liquid storage room.
a. Emergency alarm initiating devices shall be installed outside of the interior exit door.
b. Activation of an emergency alarm-initiating device shall sound a local alarm and transmit a
signal to the emergency control station.
37
c. An approved emergency telephone system, local alarm manual pull stationS or other
approved alarm-initiating devices are allowed to be used as emergency alarm-initiating
devices.
12) Portable fire extinguishers shall be provided as follows:
a. One 20-B extinguisher shall be located between 10 and 50 feet from the Liquid Storage Room
b. One shall be located within 10 feet of the Liquid Storage Room.
c. Either seven (7) 20lb or four (4) 40lb dry chemical portable extinguishers shall be provided
outside the liquid storage room IAW NFPA 10.
B. The sprinkler protection located at the Heraeus Medevio facility in Fridley will meet requirements
of the 2020 Minnesota State Building Code and 2020 Minnesota State Fire Code with the following
provisions:
1) The existing automatic sprinkler system shall be modified to provide protection in the new liquid
storage room to meet both design criteria below:
a. For storage of Isopropyl Alcohol in 55 gallon metal drums:
i. Design Density - 0.25 / entire room
ii. High temperature sprinklers
iii. 100 sqft maximum spacing
iv. 500 gpm hose demand
b. For storage of Methanol and Acetone in glass bottles:
i. Design criteria IAW FM Global Data Sheet 07-29 Table 2.4.5.1
ii. Standard response sprinklers
iii. 100 sqft maximum spacing
iv. 500 gpm hose demand
C. The Heraeus Medevio facility and storage of Flammable Liquids in the Flammable Liquid Storage
Cabinets will meet the code requirements of the 2020 Minnesota State Building Code and 2020
Minnesota State Fire Code with the following provisions:
1) A maximum of three (3) 120-gallon capacity approved cabinets are permitted with a maximum total
of 330 gallons of Class IB liquids.
2) Provide warning signs and post in locations required by the fire code official.
3) The Cabinets shall be listed IAW UL 1275.
4) Doors shall be well fitted, self-closing and equipped with a 3-point latch.
5) The cabinets shall be provided with a conspicuous label in red letters
on contrasting background that reads: FLAMMABLE – KEEP FIRE AWAY.
6) Bottom of the cabinet shall be liquid tight.
7) The combined quantity of liquids in each cabinet shall not exceed 120-
gallons or the rated cabinet capacity.
38
D. Heraeus Medevio may have the need to store Class IB flammable liquids in an outdoor location in
the future. The storage of Class IB Flammable Liquids outdoors will meet the code requirements
of the 2020 Minnesota State Building Code and 2020 Minnesota State Fire Code with the following
provisions:
1) The storage of containers outdoors in piles must not exceed 2,200 gallons and 12’-0 in height per
pile. The minimum distance between piles shall be 5 feet.
2) The minimum distance to lot line of property that can be built on is 50’-0. The minimum distance to
a public street, public alley or public way is 10 feet. The above distances can be reduced by 50% if
the quantity stored does not exceed 50% of the maximum quantity per pile.
3) Storage of containers or portable tanks shall be provided with fire apparatus access roads.
4) The storage area shall be protected against tampering or trespassers where necessary and shall be
kept free from weeds, debris and other combustible materials not necessary to the storage.
5) Storage areas shall be provided with spill control and secondary containment unless the containers
are either stored on approved containment pallets in accordance with Section 5004.2.3 or the
containers are stored in cabinets and lockers with integral spill containment.
6) Storage areas shall be protected against tampering or trespassers by fencing or other approved
control measures.
7) Guard posts or other means shall be provided to protect exterior storage tanks from vehicular
damage.
8) The storage area shall be kept free from weeds, debris and combustible materials not necessary to
the storage. The area surrounding an exterior storage area shall be kept clear of such materials for a
minimum distance of 15 feet.
9) If provided, weather protection for outdoor storage shall be in accordance with Section 5004.13.
10) Heraeus Medevio shall notify the City of Fridley in writing and submit a site storage plan for approval
prior to storing Class IB flammable liquids outdoors.
All recommendations are subject to approval and acceptance of the City of Fridley Building and Fire
Departments.
39
Appendix A – Inventory of Hazardous Materials
40
Appendix B – Material Safety Data Sheets
SAFETY DATA SHEET
1. Identification
AcetoneProduct identifier
Other means of identification
67-64-1CAS number
2-PropanoneSynonyms
General purpose solvent.Recommended use
Use in accordance with manufacturer's recommendations.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Greenfield Global USA Inc.Company Name
1101 Isaac Shelby DriveAddress
Shelbyville, KY 40065
USA
502.232.7600Telephone
502.633.6100Fax
Greenfield Global USA Inc.Company Name
58 Vale RoadAddress
Brookfield, CT 06804
USA
203.740.3471Telephone
203.740.3481Fax
Emergency phone number
CHEMTREC: 1.800.424.9300 (CCN 17213)USA
CHEMTREC: +1.703.527.3887 (CCN 17213)International
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 2Serious eye damage/eye irritationHealth hazards
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or
dizziness.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist/vapor. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Wear protective gloves/eye protection/face
protection.
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 1 / 8
Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison
center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/attention. In case of fire: Use appropriate media to extinguish.
Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Substances
2-Propanone 67-64-1 100Acetone
CAS numberCommon name and
synonyms
%Chemical name
All concentrations are in percent by weight unless otherwise indicated.Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical
attention if irritation develops and persists.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content
doesn't get into the lungs.
Ingestion
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse. Show this safety data sheet to the doctor in attendance.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed. Combustion
products may include: carbon oxides.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Use water spray to keep fire-exposed containers cool.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Highly flammable liquid and vapor.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Avoid breathing mist/vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 2 / 8
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools. The product is completely soluble in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Take precautionary measures against static discharges. All equipment used when
handling the product must be grounded. Use non-sparking tools and explosion-proof equipment.
Do not breathe mist or vapor. Avoid contact with eyes. Avoid prolonged exposure. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area
equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueMaterialType
PEL 2400 mg/m3Acetone (CAS 67-64-1)
1000 ppm
US. ACGIH Threshold Limit Values
ValueMaterialType
STEL 500 ppmAcetone (CAS 67-64-1)
TWA 250 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
ValueMaterialType
TWA 590 mg/m3Acetone (CAS 67-64-1)
250 ppm
Biological limit values
ACGIH Biological Exposure Indices
ValueMaterial Determinant Specimen Sampling Time
25 mg/l Acetone Urine *Acetone (CAS 67-64-1)
* - For sampling details, please see the source document.
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide eyewash station and safety
shower.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Chemical goggles are recommended.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Hand protection
Skin protection
Wear suitable protective clothing.Other
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 3 / 8
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Liquid.Form
Clear liquid; invisible vapor.Color
Sweet. Alcohol-like.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point -137.2 °F (-94 °C)
Initial boiling point and boiling
range
132.8 °F (56 °C)
Flash point -4.0 °F (-20.0 °C) Closed Cup
-0.4 °F (-18.0 °C) Open Cup
Evaporation rate May evaporate quickly.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
2.5 % v/v
Flammability limit - upper
(%)
12.8 % v/v
Vapor pressure 245.3 hPa at 25 °C (68 °F (20 °C))
Vapor density Not available.
Relative density 0.791 g/cm3 (77 °F (25 °C))
Solubility(ies)
Solubility (water)Completely soluble.
Auto-ignition temperature 869 °F (465 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Molecular formula C3-H6-O
Not oxidizing.Oxidizing properties
Surface tension 21.6 mN/m
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid
temperatures exceeding the flash point. Contact with incompatible materials.
Conditions to avoid
Acids. Strong oxidizing agents.Incompatible materials
No hazardous decomposition products are known.Hazardous decomposition
products
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 4 / 8
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be
harmful.
Skin contact Prolonged skin contact may cause temporary irritation.
Eye contact Causes serious eye irritation.
Ingestion May be harmful if swallowed and enters airways.
Symptoms related to the
physical, chemical and
toxicological characteristics
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsProduct Species
Acetone (CAS 67-64-1)
Dermal
Acute
LD50 Rabbit > 15700 mg/kg, 24 Hours
Inhalation
LC50 Rat 76 mg/l, 4 Hours
Vapor
Oral
LD50 Rat 5800 mg/kg
Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not regulated.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -
single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard May be harmful if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 5 / 8
Product Test ResultsSpecies
Acetone (CAS 67-64-1)
Aquatic
Acute
LC50Crustacea 8800 mg/l, 48 HoursDaphnia pulex
LC50Fish 7163 mg/l, 96 HoursPimephales promelas
Chronic
NOECCrustacea > 79 mg/l, 21 daysDaphnia magna
No data is available on the degradability of this substance. Persistence and degradability
No data available for this product.Bioaccumulative potential
The product is completely soluble in water.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not incinerate sealed
containers. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
US RCRA Hazardous Waste U List: Reference
Acetone (CAS 67-64-1) U002
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN1090UN number
Acetone (Acetone RQ = 5000 LBS)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
No.Marine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB2, T4, TP1Special provisions
150Packaging exceptions
202Packaging non bulk
242Packaging bulk
IATA
UN1090UN number
AcetoneUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIPacking group
No.Environmental hazards
3HERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 6 / 8
IMDG
UN1090UN number
ACETONEUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIPacking group
No.Marine pollutant
Environmental hazards
F-E, S-DEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not established.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not regulated.
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Flammable (gases, aerosols, liquids, or solids)
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Acetone (CAS 67-64-1) 6532
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
Acetone (CAS 67-64-1) Low priority
US state regulations
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 7 / 8
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material
is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For
more information go to www.P65Warnings.ca.gov.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Acetone (CAS 67-64-1)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS)YesAustralia
Domestic Substances List (DSL)YesCanada
Non-Domestic Substances List (NDSL)NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS)NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL)YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI)YesTaiwan
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
08-August-2018Issue date
-Revision date
Version #01
Health: 2
Flammability: 3
Physical hazard: 0
HMIS® ratings
This product is subject to Greenfield Global USA Inc.’s terms and conditions, which can be found
at http://www.greenfield.com/tc-po-us/. Greenfield cannot anticipate all conditions under which this
information and this product, or the products of other manufacturers in combination with this
product, may be used. The user is responsible for the proper and safe use, handling, storage and
disposal of the product, and assumes liability for any loss, injury, damage or expense arising from
any failure to do so. The data in this sheet is based on information and experience available at the
time of writing.
Disclaimer
Acetone SDS US
944681 Version #: 01 Revision date: - Issue date: 08-August-2018 8 / 8
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Page 1 of 12
SAFETY DATA SHEET
Isopropyl Alcohol 70%
This SDS is valid for all grades (at this concentration)
1. IDENTIFICATION OF SUBSTANCE / MIXTURE AND OF SUPPLIER
Product Identifier:High Purity Chemicals
Synonyms:Isopropanol; Isopropyl Alcohol; 2-Propanol; sec-propyl alcohol;
dimethylcarbinol; sec-propanol; Rubbing alcohol; 1-Methylethanol; IPA
70%; propan-2-ol
Other means of identification:CAS No. 67-63-0
EINECS No. 200-661-7
Recommended use of the chemical and restrictions on use:
Supplier Details:
Pharmco Products, Inc.
1101 Isaac Shelby Drive, Shelbyville,
KY 40065, USA.
Tel: 502.232.7600
Fax: 502.633.6100
CCN17213
Pharmco Products, Inc.
58 Vale Road, Brookfield,
CT 06804, USA.
Tel: 203.740.3471
Fax: 203.740.3481
CCN17213
Emergency Contact:CHEMTREC: 1.800.424.9300 (USA) / +1.703.527.3887 (International)
2. HAZARDS IDENTIFICATION
OSHA Hazards:
Flammable liquid, Target Organ Effect, Irritant
Target Organs:
Cardiovascular system, Gastrointestinal tract, Kidney, Liver, Nerves
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NFPA
GHS label elements, including precautionary statements
Signal Word:
DANGER!
Hazard statement(s)
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statement(s)
P261 Avoid breathing dust/fumes/gas/mist/vapors.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P501 Dispose of contents and container to an approved waste disposal plant.
P240 Ground/bond container and receiving equipment.
P337 + P313 If eye irritation persists: Get medical attention.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Seek
medical attention.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P303 + P361 + P353 IF ON SKIN (or hair): Remove immediately all contaminated clothing.
Rinse skin with water.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for
extinction.
P210 Keep away from heat, sparks, open flames, and hot surfaces. No
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smoking.
P233 Keep container tightly closed.
P102 Keep out of reach of children.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P243 Take precautionary measures against static discharge.
P241 Use explosion-proof electrical, ventilating, and lighting equipment.
P242 Use only non-sparking tools.
P271 Use only outdoors or in a well-ventilated area.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves and eye and face protection.
GHS Classification(s)
Eye irritation (Category 2A)
Flammable Liquids (Category 2)
Specific target organ toxicity - single exposure (Category 3)
Other hazards which do not result in classification:
Potential Health Effects:
Organ Description
Eyes Causes eye irritation.
Ingestion May be harmful if swallowed.
Inhalation May be harmful if inhaled. Causes respiratory tract irritation. Vapors may cause drowsiness and
dizziness.
Skin Harmful if absorbed through skin. Causes skin irritation.
3. COMPOSITION AND INFORMATION ON INGREDIENTS
Chemical identity:Isopropyl Alcohol 70%
Common name / Synonym:Isopropanol; Isopropyl Alcohol; 2-Propanol; sec-propyl alcohol;
dimethylcarbinol; sec-propanol; Rubbing alcohol; 1-Methylethanol; IPA
70%
CAS number:67-63-0
EINECS number:200-661-7
ICSC number:0554
RTECS #:NT8050000
UN #:UN1219
EC #:603-117-00-0
% Weight Material CAS
63 Isopropyl Alcohol 67-63-0
37 Water 7732-18-5
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4. FIRST AID MEASURES
General advice
Take proper precautions to ensure your own health and safety before attempting rescue and providing first aid.
Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area.
Skin
Immediately flush affected area with plenty of water while removing contaminated clothing. Wash contaminated
clothing before reuse. Contact a doctor. If irritation persists, get medical attention.
Inhalation
Remove person to fresh air. If signs/symptoms continue, get medical attention. Give oxygen or artificial respiration
as needed.
Eyes
Thoroughly flush the eyes with large amounts of clean low-pressure water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. If irritation persists, seek medical attention.
Ingestion
DO NOT induce vomiting. If vomiting does occur, have victim lean forward to prevent aspiration. Rinse mouth with
water. Seek medical attention. Never give anything by mouth to an unconscious individual.
5. FIRE FIGHTING MEASURES
Suitable (and unsuitable) extinguishing media:
SMALL FIRE: Use dry chemicals, CO2, water spray or alcohol-resistant foam. LARGE FIRE: Use water spray,
water fog or alcohol-resistant foam. Cool all affected containers with flooding quantities of water.
Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products):
May explode when heated. Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
Special protective equipment and precautions for firefighters:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Keep
unopened containers cool by spraying with water.
Unusual Fire and Explosion Hazards:
May produce a floating fire hazard.l
Static ignition hazard can result from handling and use.l
Vapors may travel to source of ignition and flash back.l
Vapors may settle in low or confined spaces.l
Carbon oxides expected to be the primary hazardous combustion product.
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Flammable Properties
Classification
OSHA/NFPA Class IB Flammable Liquid.
Flash point
18.3 °C (64.9 °F) - Closed Cup
Autoignition temperature
399 °C (750 °F)
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures:
Do not inhale vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel
to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low
areas.
Environmental precautions:
Stop leak. Contain spill if possible and safe to do so. Prevent product from entering drains.
Methods and materials for containment and cleaning up:
Contain spill, then collect with an electrically protected vacuum cleaner or by wet-brushing and put the material into
a convenient waste disposal container. Keep container closed.
7. HANDLING AND STORAGE
Precautions for safe handling:
Do not get on skin or in eyes. Do not inhale vapor or mist. Keep away from sources of ignition - No smoking. Take
measures to prevent the buildup of electrostatic charge. Open and handle container with care. Metal containers
involved in the transfer of this material should be grounded and bonded.
Conditions for safe storage, including any incompatibilites:
Keep container tightly closed in a dry and well- ventilated location. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters, e.g., occupational exposure limit values or biological limit values:
Occupational Exposure Limits
Component Source Type Value Note
Isopropyl Alcohol US (ACGIH)TWA 200 ppm
Isopropyl Alcohol US(ACGIH)STEL 400 ppm
Isopropyl Alcohol US (OSHA)TWA 400 ppm
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Isopropyl Alcohol US (OSHA)STEL 500 ppm
Appropriate engineering controls:
General room or local exhaust ventilation is usually required to meet exposure limit(s). Electrical equipment should
be grounded and conform to applicable electrical code.
Individual protection measures, such as personal protective equipment:
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the
respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components
tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection:
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching
glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in
accordance with applicable laws and good laboratory practices. Wash and dry hands.
Eye protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Use equipment approved by
appropriate government standards, such as NIOSH (US) or EN166 (EU) Maintain eye wash fountain and
quick-drench facilities in work area.
Skin and body protection:
Wear impervious, flame retardant, antistatic protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact.
Hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end
of workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance (physical state, color, etc.)Liquid. Colorless, clear.
Freezing point -89 °C (-127 °F)
Initial boiling point and boiling range 83 °C (181°F)
Flash point 18.3 °C (64.9 °F) - Closed Cup
Flammability (solid, gas)Flammable
Upper / Lower flammability or explosive limits 2% (V) / 12.7% (V)
Vapor pressure 43.2 hPa (32.4 mmHg) at 20.0 °C (68.0 °F)
Vapor Density 2.1
Solubility(ies)soluble
Auto-ignition temperature 399 °C (750°F)
Formula (ISOPROPYL ALCOHOL)C3H8O
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Formula (WATER)H2O
Molecular Weight (ISOPROPYL ALCOHOL)60.1 g/mol
Molecular Weight (WATER)18.02 g/mol
10. STABILITY AND REACTIVITY
Possibility of hazardous reactions Vapors may form explosive mixture with air.
Conditions to avoid (e.g., static discharge,
shock or vibration)
Heat, flames, and sparks. Extreme temperatures and direct
sunlight.
Incompatible materials Oxidizing agents, Acid anhydrides, Aluminium, Halogenated
compounds, Acids
Hazardous decomposition products Hazardous decomposition products formed under fire conditions. -
Carbon oxides
11. TOXICOLOGICAL INFORMATION
Water 7732-18-5l
Product Summary:
Do data available for the teratogenic, mutagenic, or reproductive toxicity effects of this product.
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable or
confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by OSHA.
Other Hazards
Organ Description
Inhalation May cause respiratory tract irritation upon inhalation.
Isopropyl Alcohol 67-63-0l
Product Summary:
Long-term exposure (2 years) to Isopropyl Alcohol via inhalation at concentrations up to 5000 ppm caused no
exposure related increases in tumors in animals. No data available for the teratogenicity, mutagenicity, or
Product Information: 203.740.3471 Emergency Assistance (CHEMTREC): 1.800.424.9300 (USA)
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reproductive toxicity of this product. No data available to designate the product as causing specific target organ
toxicity through repeated exposure. No data available to designate product as an aspiration hazard.
Acute Toxicity:
LC50 (vapor)Rat 19,000 ppm 8 hours
LD50 (oral)Rat 4,396 mg/kg
LD50 (skin)Rabbit 12,870 mg/kg
Irritation:
Eyes (ISOPROPANOL)
Mildly irritating to the eye at an airborne concentration of 400 ppm, unpleasant at 800 ppm.
Skin
Moderate skin irritant
Eyes
Rabbit - Irritating to eyes - 24 hours
Carcinogenicity
IARC: Group 3: Not classifiable as to its carcinogenicity to humans.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by OSHA.
Other Hazards
Organ Description
Eyes Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible
corneal injury. May cause transient corneal injury
Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May
cause central nervous system depression, characterized by excitement, followed by headache, dizziness,
drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible
death due to respiratory failure.
Inhalation
Inhalation of high concentrations may cause central nervous system effects characterized by nausea,
headache, dizziness, unconsciousness and coma. May cause narcotic effects in high concentration.
Causes upper respiratory tract irritation. Inhalation of vapors may cause drowsiness and dizziness.
Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. The probable
oral lethal dose in humans is 240 ml (2696 mg/kg), but ingestion of only 20 ml (224 mg/kg) has caused
poisoning.
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Skin
May cause irritation with pain and stinging, especially if the skin is abraded. Isopropanol has a low
potential to cause allergic skin reactions; however, rare cases of allergic contact dermatitis have been
reported. May be absorbed through intact skin. Dermal absorption has been considered toxicologically
insignificant.
Chronic Prolonged exposure can be irritating to mucous membranes, skin, and the respiratory system. Can
cause liver and kidney damage.
12. ECOLOGICAL INFORMATION
Water 7732-18-5l
Ecotoxicity (aquatic and terrestrial, where available):
Ecotoxicity
Not Applicable
Persistence and degradability:
No data available
Bioaccumulative potential:
No data available
Other adverse effects:
No data available
Isopropyl Alcohol 67-63-0l
Ecotoxicity (aquatic and terrestrial, where available):
Acute Fish Toxicity (ISOPROPANOL)
LC50 / 96 hours Pimephales promelas: 9,640 mg/L
Toxic to Daphnia and Other Aquatic Invertebrates
EC50 / 24 h / Water Flea - 5,102 mg/L
Toxicity to Aquatic Plants (ISOPROPANOl)
EC50 / 72 hours Scenedesmus subspicatus > 1,000 mg/L
Persistence and degradability:
No data available
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Bioaccumulative potential:
No data available
13. DISPOSAL CONSIDERATIONS
Description of waste residues and information on their safe handling and methods of disposal, including the
disposal of any contaminated packaging:
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a
licensed professional waste disposal service to dispose of this material.
14. TRANSPORT INFORMATION
Description of waste residues and information on their safe handling and methods of disposal:
UN number UN1219
UN proper shipping name Isopropanol
Transport hazard class(es)3
Packing group (if applicable)II
IMDG
UN-Number: UN1219 Class: 3 Packing Group: II
EMS-No: F-E, S-D
Proper shipping name: ISOPROPANOL
Marine pollutant: No
IATA
UN-Number: UN1219 Class: 3 Packing Group: II
Proper shipping name: Isopropanol
15. REGULATORY INFORMATION
Safety, health and environmental regulations specific for the product in question:
OSHA Hazards
Flammable liquid, Target Organ Effect, Irritant
All ingredients are on the following inventories or are exempted from listing
Country Notification
Australia AICS
Canada DSL
China IECS
European Union EINECS
Japan ENCS/ISHL
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Korea ECL
New Zealand NZIoC
Philippines PICCS
United States of America TSCA
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA title III, Section 313: ISOPROPYL
ALCOHOL (CAS# 67-63-0) Revision date: 1987-01-01.
SARA 311/312 Hazards
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
CERCLA
No chemicals in this material with known CAS numbers are subject to the reporting requirements of CERCLA
Massachusetts Right To Know Components
Isopropyl Alcohol CAS-No. 67-63-0 Revision Date 1987-01-01
Pennsylvania Right To Know Components
Isopropyl Alcohol CAS-No. 67-63-0 Revision Date 1987-01-01
Water CAS-No. 7732-18-5
New Jersey Right To Know Components
Isopropyl Alcohol CAS-No. 67-63-0 Revision Date 1987-01-01
Water CAS-No. 7732-18-5
California Prop 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any
other reproductive harm.
16. OTHER INFORMATION:
Product Information: 203.740.3471 Emergency Assistance (CHEMTREC): 1.800.424.9300 (USA)
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INCLUDING INFORMATION ON PREPARATION AND REVISION OF THE SDS
Disclaimer
PHARMCO-AAPER believes that the information on this SDS was obtained from reliable sources. However, the
information is provided without any warranty, expressed or implied, regarding its correctness. Some information
presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The
conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be
beyond our knowledge. For this and other reasons, PHARMCO-AAPER does not assume responsibility and
expressly disclaims liability for loss, damage, or expense arising out of or in any way connected with handling,
storage, use, or disposal of this product. If the product is used as a component in another product, this SDS
information may not be applicable. Information is correct to the best of our knowledge at the date of the SDS
publication.
Page 1 / 6
SECTION 2. Hazard(s) Identification
Safety Data Sheet
according to OSHA Hazard Communication
29 CFR Part 1910.1200
SECTION 1. Identification
Product Code
03-101
24 Hour Emergency:
Transportation:
1-800-424-9300
Health: 1-800-356-3129
NOTE: Emergency numbers to be used only in the
event of chemical emergencies involving a spill,
leak, fire, exposure or accident involving chemicals
Product Name: Isopropyl Alcohol 99% USP Kosher
Supplied by:
Chemical Marketing Corporation
9945 Flanders Court NE
Blaine, MN 55449
(763) 785-0055
E-Mail: sbaker@chemmktg.com
*** EMERGENCY OVERVIEW ***: Highly flammable liquid and vapor.
GHS Classification
Eye Irrit. 2, Flam. Liq. 2, STOT SE 3 NE
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Flammable Liquid, category 2 H225 Highly flammable liquid and vapor.
Eye Irritation, category 2 H319 Causes serious eye irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS PRECAUTIONARY STATEMENTS
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor/physician if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
Page 2 / 6
SECTION 3. Co mposition/Information on Ingredients
P370+P378 In case of fire: Use appropriate method to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Chemical Name
CAS-No.
Wt. %
GHS Symbols
GHS Statements
2-propanol 67-63-0 75-100 GHS02-GHS07 H225-319-336
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
FIRST AID - EYE CONTACT: Immediately flush eyes with water. Flush eyes with water for a minimum of 15 minutes, occasionally
lifting and lowering upper lids. Get medical attention promptly. Remove contact lenses if worn.
FIRST AID - SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and water. Get medical attention. Wash clothing
separately and clean shoes before reuse.
FIRST AID - INHALATION: Rescuers should put on appropriate protective gear. Remove from area of exposure. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Keep victim warm. Get immediate medical attention. To prevent
aspiration, keep head below knees.
FIRST AID - INGESTION: Do not induce vomiting. Do not give liquids. Obtain emergency medical attention.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Highly flammable liquid and vapor. Vapors/dust may cause flash fire or explosion.
Vapors can travel to a source of ignition and flash back. Empty containers retain product residue (liquid and/or vapor) and can be
dangerous. DO NOT pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, stati c
electricity, or other sources of ignition. Also, do not reuse container without commercial clean ing or reconditioning.
SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH
approved or equivalent) and full protective gear. Avoid use of solid water streams. Water spray to cool containers or protect
personnel. Use with caution. Use water spray to knock down vapors. Water runoff can cause environmental damage. Dike and
collect water used to fight fire.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASE OR SPILLED: Wear appropriate personal protective equipment. (See
Exposure Controls / Personal Protection Section.)Eliminate all ignition sources. Prevent additional discharge of material if able to do
so safely. Do not touch or walk through spilled material. Avoid runoff into storm sewers and ditches which lead to waterway s.
Ventilate spill area. Stay upwind of spill. A vapor supressing foam may be used to reduce vapors. If leak or spill has not ignited, use
water spray to disperse the vapors. Collect spilled materials for disposal. Use only non -combustible material for clean-up. Use
clean, non-sparking tools to collect absorbed materials. Absorb spill with inert material (e.g. dry sand or earth), then place in a
chemical waste container. Recover by pumping (use an explosion proof or hand pump).
HANDLING: Use only in a well ventilated area. Avoid breathing vapor, fumes or mist. Avoid contact with eyes, skin, and clothing.
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Always open
containers slowly to allow any excess pressure to vent. Follow all MSDS/label precautions even after containers are emptied
because they may retain product residues.
STORAGE: Keep away from heat, sparks, and flame. Store containers in a cool, well ventilated place. Keep container closed when
not in use. Protect from direct sunlight.
SECTION 7. Handling and Storage
SECTION 6. Accidental Release Measures
SECTION 5. Fire-Fighting Measures
SECTION 4. First-Aid Measures
Page 3 / 6
SECTION 9. Physical and Chemical Properties
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING
2-propanol 200 ppm 400 ppm 400 ppm N.D.
Personal Protection
RESPIRATORY PROTECTION: NIOSH/MSHA approved respirators may be necessary if airborne concentrations are
expected to exceed exposure limits.
SKIN PROTECTION: Wear impervious protective gloves. Wear long sleeves when contact is likely to occur. Wear
protective gear as needed - apron, suit, boots.
EYE PROTECTION: Use chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent).
OTHER PROTECTIVE EQUIPMENT: Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.
HYGENIC PRACTICES: Do not eat, drink, or smoke in areas where this material is used. Avoid breathing vapors.
Remove contaminated clothing and wash before reuse. Wash thoroughly after handling. Wash hands before eating.
Appearance:
Clear, colorless liquid Physical State:
Liquid
Odor: Typical Odor Threshold: N.D.
Density, g/cm3:
Freeze Point, °F:
0.790
N.D.
pH:
Viscosity:
N.D.
N.D.
Solubility in Water: Soluble Explosive Limits, vol%: 2.0 - 12.0
Boiling Range, °F: 180 - 181 Flash Point, °F: 53
Evaporation Rate: 2.88 (n-Bu Acetate=1) Auto-ignition Temp., °F: N.D.
Vapor Density: 2.08 Vapor Pressure: 32.25 mm Hg @ 20C
(See "Other information" Section for abbreviation legend)
STABILITY: No Information
CONDITIONS TO AVOID: Avoid impact, friction, heat, sparks, flame and source of ignition.
INCOMPATIBILITY: Avoid contact with caustics. Prevent contact with inorganic acids. Prevent contact with aldehydes. Avoid
contact with chlorinated compounds. Prevent contact with halogens. Prevent contact with strong oxidizing agents. Avoid contact
with amines.
HAZARDOUS DECOMPOSITION PRODUCTS: Toxic gases/fumes are given off during burning or thermal decomposition. During
combustion carbon monoxide may be formed. During combustion carbon dioxide may be formed.
HAZARDOUS POLYMERIZATION: No Information
SECTION 10. Stability and Reactivity
SECTION 8. Exposure Controls/Personal Protection
Page 4 / 6
SECTION 11. Toxicological Information
SECTION 12. Ecological Information
Information on Toxicological Effects
EFFECTS OF OVEREXPOSURE - INHALATION: Vapors can cause irritation of the respiratory tract. High concentrations can cause
headache, nausea, weakness, lightheadedness, and stupor (CNS depression).
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Prolonged or repeated contact can result in defatting
and drying of the skin which may result in skin irritation and dermatitis (rash).
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Moderately irritating to the eyes causing transient corneal injury.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful or fatal if liquid is aspirated into lungs. Incidentally swallowing small
amounts as a result of normal handling operations is not likely to cause injury; however, swallowing larger amounts may cause injury.
Overexposure may cause nausea, diarrhea, and/or vomiting. May cause central nervous system depression.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Overexposure may cause nervous system damage. Small amounts of
liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Vapors
irritating to eyes and respiratory tract. A component of this product is a potential hazard to the fetus.
Primary Route(s) of Entry: Eye Contact, Ingestion, Inhalation, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Name according to EEC Oral LD50, mg/kg Dermal LD50, mg/kg Vapor LC50, mg/L
67-63-0 2-propanol 5,840 >12,800 >9988.0
ECOLOGICAL INFORMATION: No Information
Always dispose of any waste in accordance with all local, state, and federal regulations.
DISPOSAL METHOD: Dispose of waste in accordance with all local, state and federal regulations.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASE OR SPILLED: Wear appropriate personal protective equipment. (See
Exposure Controls / Personal Protection Section.)Eliminate all ignition sources. Prevent additional discharge of material if able to do
so safely. Do not touch or walk through spilled material. Avoid runoff into storm sewers and ditches which lead to waterways.
Ventilate spill area. Stay upwind of spill. A vapor supressing foam may be used to reduce vapors. If leak or spill has not ignited, use
water spray to disperse the vapors. Collect spilled materials for disposal. Use only non -combustible material for clean-up. Use
clean, non-sparking tools to collect absorbed materials. Absorb spill with inert material (e.g. dry sand or earth), then place in a
chemical waste container. Recover by pumping (use an explosion proof or hand pump).
DOT Proper Shipping
Name:
Isopropanol Packing Group: II
DOT Hazard Class: 3 Hazard SubClass: No Information
DOT UN/NA Number: UN1219 Resp. Guide Page: 129
SECTION 14. Transport Information
SECTION 13. Disposal Considerations
Page 5 / 6
SECTION 15. Re gulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA components exist in this product.
U.S. State Regulations:
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five components in this product.
No NJ Right-To-Know components exist in this product.
PENNSYLVANIA RIGHT-TO-KNOW
The following non-hazardous ingredients are present in the product are at or greater than 3%.
No PA Right-To-Know components exist in this product.
CALIFORNIA PROPOSITION 65 CARCINOGENS
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
No Proposition 65 Carcinogens exist in this product.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations: As follows -
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
WHMIS Class: No Information
Page 6 / 6
SECTION 16. Other Information
Revision Date: 10/20/2014 Supersedes Date: New SDS
Datasheet produced by: EH&S - Regulatory Department
HMIS Ratings:
Health: 1 Flammability: 3 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds, gr/ltr: 100
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS07
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined, N.I. - No Information
The information on this SDS was obtained from sources which we believe to be reliable. However, the information provided is
without any warranty, expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein
are from sources other than direct test data on the product itself. The information and recommendations are offered for the user's
consideration and examination and should be used to make an independent determination of the methods to safeguard workers and
the environment. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For these reasons we do not assume responsibility and expressly disclaim any liability for loss, damage,
or expense arising out of or in any way connected with handling, storage, use, or disposal of this product. If the product is used as a
component in another product, this SDS may not be applicable. It is the responsibility of the user to comply with all Federal, State,
and Local laws and regulations.
DISCLAIMER: THE VOLATILE ORGANIC COMP OUND (VOC) CONTENT REPORTED HEREIN, IF ANY, IS BASED ON A MATERIAL VOC
CALCULATION. NOTE THAT SEVERAL METHODS ARE USED FOR CALCULATING VOC CONTENT AND THAT STANDARDS/
REQUIREMENTS REGARDING VOC CONTENT VARY BY LOCATION/JURISDICTION. ACCORDINGLY, EMCO MAKES NO
REPRESENTATIONS OR WARRANTIES, EXPRESS OR IMPLIED, REGARDING THIS MATERIAL’S COMPLIANCE WITH VOC STANDARDS/
REQUIREMENTS APPLICABLE IN LOCATIONS/JURISDICTIONS WHERE THIS MATERIAL MAY BE SOLD OR USED.
SAFETY DATA SHEET
1. Identification
MethanolProduct identifier
Other means of identification
67-56-1CAS number
General purpose solvent.Recommended use
Use in accordance with manufacturer's recommendations.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Greenfield Global USA Inc.Company Name
1101 Isaac Shelby DriveAddress
Shelbyville, KY 40065
USA
502.232.7600Telephone
502.633.6100Fax
Greenfield Global USA Inc.Company Name
58 Vale RoadAddress
Brookfield, CT 06804
USA
203.740.3471Telephone
203.740.3481Fax
Emergency phone number
CHEMTREC: 1.800.424.9300 (CCN 17213)USA
CHEMTREC: +1.703.527.3887 (CCN 17213)International
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 3Acute toxicity, oralHealth hazards
Category 3Acute toxicity, dermal
Category 3Acute toxicity, inhalation
Category 1 (central nervous system, optic
nerve)
Specific target organ toxicity, single exposure
(inhalation)
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled.
Causes damage to organs (central nervous system, optic nerve) by inhalation.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling.
Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing. Wear protective gloves/eye protection/face protection.
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 1 / 8
Response If swallowed: Immediately call a poison center/doctor. Rinse mouth. If on skin (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person
to fresh air and keep comfortable for breathing. Call a poison center/doctor. Take off immediately
all contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to
extinguish.
Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Substances
67-56-1 100Methanol
CAS numberCommon name and
synonyms
%Chemical name
All concentrations are in percent by weight unless otherwise indicated.Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Call a poison center or doctor/physician.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical
advice/attention if you feel unwell. Get medical attention if irritation develops and persists. Wash
contaminated clothing before reuse.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use
mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of
a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Ingestion
Narcosis. Headache. Dizziness. Nausea, vomiting. Behavioral changes. Decrease in motor
functions. Direct contact with eyes may cause temporary irritation. Methanol: Human exposure to
methanol may result in illness, systemic poisoning, blindness, optic nerve damage and perhaps
death, after being ingested, absorbed through the skin or inhaled. Death due to cardiac or
respiratory failure has been reported in some cases from consumption of as little as 30 mls.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under
observation. Symptoms may be delayed. Provide standard methanol ingestion treatment. To
prepare the antidote, make a solution using 100 mL of 100-proof ethyl alcohol (grain alcohol) in
2000 mL of water and give 1.5 mL/kg of body weight, or 100 mL for an average adult. Following
this, at 2 hour intervals for 4 days, give the antidote (0.5-1.0 mL/kg of body weight, orally or
intravenously) to reduce the metabolism of the methanol and to allow time for its excretion. Blood
ethanol levels should be 1.0-1.5 mg/mL.
Indication of immediate
medical attention and special
treatment needed
Take off immediately all contaminated clothing. If you feel unwell, seek medical advice (show the
label where possible). Ensure that medical personnel are aware of the material(s) involved, and
take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
Wash contaminated clothing before reuse.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed. Combustion
products may include: carbon oxides.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Use water spray to keep fire-exposed containers cool.
Fire fighting
equipment/instructions
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 2 / 8
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Highly flammable liquid and vapor.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take
precautionary measures against static discharges. All equipment used when handling the product
must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or
swallow. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do
not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Wear appropriate personal
protective equipment. Wash hands thoroughly after handling. Wash contaminated clothing before
reuse. Observe good industrial hygiene practices.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area
equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueMaterialType
PEL 260 mg/m3Methanol (CAS 67-56-1)
200 ppm
US. ACGIH Threshold Limit Values
ValueMaterialType
STEL 250 ppmMethanol (CAS 67-56-1)
TWA 200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
ValueMaterialType
STEL 325 mg/m3Methanol (CAS 67-56-1)
250 ppm
TWA 260 mg/m3
200 ppm
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 3 / 8
Biological limit values
ACGIH Biological Exposure Indices
ValueMaterial Determinant Specimen Sampling Time
15 mg/l Methanol Urine *Methanol (CAS 67-56-1)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Methanol (CAS 67-56-1) Skin designation applies.
US - Tennessee OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Methanol (CAS 67-56-1) Can be absorbed through the skin.
Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide eyewash station and safety shower.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Nitrile, butyl rubber or neoprene gloves are
recommended. Other suitable gloves can be recommended by the glove supplier. Be aware that
the liquid may penetrate the gloves. Frequent change is advisable.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Respirator type: Chemical respirator with
organic vapor cartridge and full facepiece.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Keep away from food and drink. Always observe good personal
hygiene measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Liquid.Form
Clear. Colorless.Color
Not available.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing point -144.4 °F (-98 °C)
Initial boiling point and boiling
range
147.2 °F (64 °C) 101.325 kPa
Flash point 51.8 °F (11.0 °C) Closed Cup
Evaporation rate Not available.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
6 %
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 4 / 8
Flammability limit - upper
(%)
36 %
Vapor pressure 130.3 hPa (68 °F (20 °C))
Vapor density 1.1
Relative density 0.791 g/ml (77 °F (25 °C))
Solubility(ies)
Solubility (water)Completely miscible
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 867.2 °F (464 °C)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Molecular formula C-H4-O
Molecular weight 32.04 g/mol
Not oxidizing.Oxidizing properties
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid
temperatures exceeding the flash point. Contact with incompatible materials.
Conditions to avoid
Strong oxidizing agents.Incompatible materials
No hazardous decomposition products are known.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Toxic if inhaled. Causes damage to organs by inhalation.
Skin contact Toxic in contact with skin.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Toxic if swallowed.
Symptoms related to the
physical, chemical and
toxicological characteristics
Narcosis. Headache. Dizziness. Nausea, vomiting. Behavioral changes. Decrease in motor
functions. Direct contact with eyes may cause temporary irritation. Methanol: Human exposure to
methanol may result in illness, systemic poisoning, blindness, optic nerve damage and perhaps
death, after being ingested, absorbed through the skin or inhaled. Death due to cardiac or
respiratory failure has been reported in some cases from consumption of as little as 30 mls.
Information on toxicological effects
Acute toxicity Toxic if inhaled. Toxic in contact with skin. Toxic if swallowed.
Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation
Direct contact with eyes may cause temporary irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 5 / 8
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not regulated.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -
single exposure
Causes damage to organs (central nervous system, optic nerve) by inhalation.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
The product is readily biodegradable. Persistence and degradability
The product is not expected to bioaccumulate.Bioaccumulative potential
No data available.Mobility in soil
This product is miscible in water.Mobility in general
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not incinerate sealed
containers. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
US RCRA Hazardous Waste U List: Reference
Methanol (CAS 67-56-1) U154
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN1230UN number
Methanol (Methanol RQ = 5000)UN proper shipping name
3Class
Transport hazard class(es)
NoneSubsidiary risk
3Label(s)
IIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB2, T7, TP2Special provisions
150Packaging exceptions
202Packaging non bulk
242Packaging bulk
IATA
UN1230UN number
MethanolUN proper shipping name
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 6 / 8
3Class
Transport hazard class(es)
6.1Subsidiary risk
3
+6.1
Label(s)
IIPacking group
NoEnvironmental hazards
3PERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1230UN number
MethanolUN proper shipping name
3Class
Transport hazard class(es)
6.1Subsidiary risk
3
+6.1
Label(s)
IIPacking group
NoMarine pollutant
Environmental hazards
F-E, S-DEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not established.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Methanol (CAS 67-56-1) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not regulated.
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Flammable (gases, aerosols, liquids, or solids)
Acute toxicity (any route of exposure)
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Chemical name % by wt.CAS number
Methanol 10067-56-1
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Methanol (CAS 67-56-1)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Contaminate candidate listSafe Drinking Water Act
(SDWA)
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 7 / 8
US state regulations
US. Massachusetts RTK - Substance List
Methanol (CAS 67-56-1)
US. New Jersey Worker and Community Right-to-Know Act
Methanol (CAS 67-56-1)
US. Pennsylvania Worker and Community Right-to-Know Law
Methanol (CAS 67-56-1)
US. Rhode Island RTK
Methanol (CAS 67-56-1)
California Proposition 65
This product can expose you to Methanol, which is known to the State of California to cause birth
defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 - CRT: Listed date/Developmental toxin
Methanol (CAS 67-56-1) Listed: March 16, 2012
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Methanol (CAS 67-56-1)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS)YesAustralia
Domestic Substances List (DSL)YesCanada
Non-Domestic Substances List (NDSL)NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS)NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL)YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI)YesTaiwan
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
11-June-2018Issue date
29-June-2018Revision date
Version #02
Health: 4
Flammability: 3
Physical hazard: 0
HMIS® ratings
This product is subject to Greenfield Global USA Inc.’s terms and conditions, which can be found
at http://www.greenfield.com/tc-po-us/. Greenfield cannot anticipate all conditions under which this
information and this product, or the products of other manufacturers in combination with this
product, may be used. The user is responsible for the proper and safe use, handling, storage and
disposal of the product, and assumes liability for any loss, injury, damage or expense arising from
any failure to do so. The data in this sheet is based on information and experience available at the
time of writing.
Disclaimer
Methanol SDS US
944153 Version #: 02 Revision date: 29-June-2018 Issue date: 11-June-2018 8 / 8